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N-Phenyl-2-naphthylamine
CAS No.: 135-88-6
Synonyms:
Formula: C16H13N
Exact Mass: 219.10500
Molecular Weight: 219.28100
PSA: 12.03000
LogP: 4.65640
Reference Price: $185/kg Inquiry Now
N-Phenyl-2-naphthylamine 135-88-6 MSDS
  N-Phenyl-2-naphthylamine
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        N-Phenyl-2-naphthylamine    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified    
  HEALTH HAZARDS
  Skin corrosion/irritation        Category 2    
    Category 2A
  Serious eye damage/eye irritation
  Skin sensitization        Category 1    
    Category 2
  Carcinogenicity
  ENVIRONMENTAL HAZARDS
    Category 2
  Acute aquatic hazard
  Long-term aquatic hazard        Category 2    
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
    Warning
  Signal word
  Hazard statements        Causes skin irritation    
    Causes serious eye irritation
    May cause an allergic skin reaction
    Suspected of causing cancer
    Toxic to aquatic life
    Toxic to aquatic life with long lasting effects
  Precautionary statements:
    Obtain special instructions before use.
  [Prevention]
    Do not handle until all safety precautions have been read and understood.
    Avoid breathing dust/fume/gas/mist/vapours/spray.
    Avoid release to the environment.
    Contaminated work clothing should not be allowed out of the workplace.
    Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  N-Phenyl-2-naphthylamine

Section 2. HAZARDS IDENTIFICATION
  [Response]        IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,    
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation or rash occurs: Get medical advice/attention.
    Wash contaminated clothing before reuse.
    IF exposed or concerned: Get medical advice/attention.
    Collect spillage.
  [Storage]        Store locked up.    
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government.
  Other hazards which do not        Dust explosion possible if in powder or granular form, mixed with air.    
  result in classification

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
    N-Phenyl-2-naphthylamine
  Components:
  Percent:        >97.0%(N)    
  CAS Number:        135-88-6    
  Synonyms:        2-Anilinonaphthalene    
  Chemical Formula:        C16H13N    

Section 4. FIRST AID MEASURES
    Remove victim to fresh air and keep at rest in a position comfortable for breathing.
  Inhalation:
    Get medical advice/attention.
    Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
  Skin contact:
    soap and water. Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Get medical advice/attention.
  Ingestion:        Get medical advice/attention.Rinse mouth.    
  Most important        Redness, Pain    
  symptoms/effects, acute
  and delayed:
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-    
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.    
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use extra personal protective equipment (P3 filter respirator for toxic particles). Keep
  Personal precautions,
  protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should
  emergency procedures: be controlled around the leakage area by roping off, etc.
  Environmental precautions: Be careful not to let it flow into rivers, etc., since adverse effects on the environment
    are concerned.
  N-Phenyl-2-naphthylamine

Section 6. ACCIDENTAL RELEASE MEASURES
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a closed system if possible. Use a local exhaust if dust or aerosol will be
    generated.
  Advice on safe handling: Avoid all contact!
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.    
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
    Comply with laws.
  Packaging material:

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.    
  Personal protective equipment
  Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator,
    etc. Use respirators approved under appropriate government standards and follow
    local and national regulations.
    Impervious gloves.
  Hand protection:
  Eye protection:        Safety goggles. A face-shield, if the situation requires.    
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid    
  Form:        Crystal- Powder    
    White - Greyish reddish yellow
  Colour:
  Odour:        No data available    
  pH: No data available
  Melting point/freezing point:108°C
    237°C/2kPa
  Boiling point/range:
  Flash point:        No data available    
  Flammability or explosive
  limits:
  Lower:        No data available    
  Upper:        No data available    
  Relative density:        No data available    
  Solubility(ies):
    Insoluble
  [Water]
  [Other solvents]
  Soluble:        Ether, Alcohols, Benzene, Acetone, Acetic acid    
  Log Pow:        4.38    

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.    
  Possibility of hazardous Dust explosion possible if in powder or granular form, mixed with air.
  reactions:
    Static discharge
  Conditions to avoid:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
  products:
  N-Phenyl-2-naphthylamine

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        orl-mus LD50:1450 mg/kg    
    orl-rat LD50:8730 mg/kg
  Skin corrosion/irritation: No data available
  Serious eye        No data available    
  damage/irritation:
  Germ cell mutagenicity: cyt-mus-orl 360 mg/kg/18D
    mmo-sat 50 pph (+S9)
    mtr-hmn-oth 23100 ug/L
  Carcinogenicity:        orl-mus TDLo:433 g/kg/2Y-C    
    scu-mus TDLo:464 mg/kg
  IARC =        Group 3 (Not classifiable as carcinogenic to humans)    
  NTP =        No data available    
  Reproductive toxicity:        No data available    
    QM4550000
  RTECS Number:

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
    48h LC50:1.2 ppm (Oryzias latipes)
  Fish:
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: 0% (by BOD), 5.3% (272nm), 4.0% (302nm) (by UV-VIS), 3.6% (by GC)
  Bioaccumulative        <5 (conc. 0.3 mg/L), <50 (conc. 0.03 mg/L)    
  potential(BCF):
  Mobility in soil
  Log Pow:        4.38    
    12500
  Soil adsorption (Koc):
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        9: Miscellaneous dangerous goods.    
    3077
  UN-No:
  Proper shipping name:        Environmentally hazardous substance, solid, n.o.s.    
  Packing group:        III    
  Marine pollutant        Y    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  The list of a dangerous chemical(2002)/CN-No.: 61834
  N-Phenyl-2-naphthylamine


SECTION 16 - ADDITIONAL INFORMATION
N/A

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