Nickel nitrate hexahydrate
CAS No.: 13478-00-7
Synonyms:
Formula: H12N2NiO12
Exact Mass: 289.97400
Molecular Weight: 290.79500
PSA: 193.14000
LogP: 0.18240
Nickel nitrate hexahydrate 13478-00-7 MSDS
Name: Nickel(II) Nitrate Hexahydrate 99% Material Safety Data Sheet
Synonym: Nickelous Nitrate Hexahydrate; Nitric Acid Nickel (II) Salt Hexahydrate
CAS: 13478-00-7
Section 1 - Chemical Product   MSDS Name:Nickel(II) Nitrate Hexahydrate 99% Material Safety Data Sheet
Synonym:Nickelous Nitrate Hexahydrate; Nitric Acid Nickel (II) Salt Hexahydrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
13478-00-7 NICKEL(II) NITRATE, HEXAHYDRATE 99 unlisted
Hazard Symbols: XN O
Risk Phrases: 20/22 8

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Contact with combustible material may cause fire.Oxidizer.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis.
Skin:
Causes skin irritation. May cause severe irritation and possible burns. May cause dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage.
Inhalation:
Dust is irritating to the respiratory tract. Inhalation of vapor may cause respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea (labored breathing), and death.
Chronic:
Prolonged inhalation may cause respiratory tract inflammation and lung damage. Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration.
May cause respiratory tract cancer.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Substance is nonflammable. Oxidizer. Greatly increases the burning rate of combustible materials. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Containers may explode if exposed to fire.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. For large fires flood fire with water from a distance. Do NOT use dry chemicals, CO2, Halon or foams.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Wear a self contained breathing apparatus and appropriate Personal protection. (See Exposure Controls, Personal Protection section). Avoid generating dusty conditions. Remove all sources of ignition. Carefully scoop up and place into appropriate disposal container. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Wash clothing before reuse.
Storage:
Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from reducing agents.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Appearance: emerald green
Odor: odorless
pH: 4.0 (aqueous sol.)
Vapor Pressure: Negligible
Viscosity: Not available.
Boiling Point: 137 deg C
Freezing/Melting Point: 57 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 200 C
Solubility in water: 238.5g/100cc water @ 20C.
Specific Gravity/Density: 2.05
Molecular Formula: Ni(NO3)26H2O
Molecular Weight: 290.8

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, combustible materials, flammable materials.
Incompatibilities with Other Materials:
Alkyl esters, aluminum, hydroxylamine, phosphinates, phosphorus, strong reducing agents, strong acids, sulfur, tin (II) chloride.
Hazardous Decomposition Products:
Nitrogen oxides, irritating and toxic fumes and gases, nitrogen, nickel oxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 13478-00-7: QR7300000 LD50/LC50:
CAS# 13478-00-7: Oral, rat: LD50 = 1620 mg/kg.
Carcinogenicity:
NICKEL(II) NITRATE, HEXAHYDRATE - ACGIH: A5 - Not Suspected as a Human Carcinogen (listed as ** und California: carcinogen; initial date 10/1/89 (listed as ** undefined * NIOSH: occupational carcinogen (listed as ** undefined **) NTP: Suspect carcinogen (listed as ** undefined **).
OSHA: Possible select carcinogen (listed as ** undefined **).
IARC: Group 2B carcinogen (listed as ** undefined **).
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: NICKEL NITRATE
Hazard Class: 5.1
UN Number: 2725
Packing Group: III
IMO
Shipping Name: NICKEL NITRATE
Hazard Class: 5.1
UN Number: 2725
Packing Group: III
RID/ADR
Shipping Name: NICKEL NITRATE
Dangerous Goods Code: 5.1(22C)
UN Number: 2725

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 24/25 Avoid contact with skin and eyes.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13478-00-7: No information available.
United Kingdom Occupational Exposure Limits
CAS# 13478-00-7: OES-United Kingdom, TWA (listed as ** undefined
**): 1 mg/m3 TWA
CAS# 13478-00-7: OES-United Kingdom, STEL (listed as ** undefined
**): 3 mg/m3 STEL
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13478-00-7 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 13478-00-7: OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3
OEL-AUSTRALIA:TWA 1 mg(Ni)/m3
OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-BELGIUM:TWA 1 mg(Ni)/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Ni)/m3;STEL 0.25 mg(Ni)/m3
OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen
OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Carcinogen
OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;CAR (insoluble compounds)
OEL-FRANCE:TWA 1 mg(Ni)/m3
OEL-GERMANY;Carcinogen
OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;CAR (insoluble compounds)
OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen
OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen
OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3
OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3
OEL-RUSSIA:STEL 0.05 mg(Ni)/m3
OEL-SWEDEN:TWA 0.5 mg(Ni)/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds)
OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN9
OEL-THAILAND:TWA 1 mg(Ni)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds)
OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 13478-00-7 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).


SECTION 16 - ADDITIONAL INFORMATION
N/A

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