1-naphthylamine 134-32-7 MSDS
  1-Naphthylamine      Revision number: 5    
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        1-Naphthylamine    
    
  Revision number:        5    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified    
  HEALTH HAZARDS
  Acute toxicity (Oral)        Category 4    
    Category 3
  Acute toxicity (Dermal)
  Serious eye damage/eye irritation        Category 2B    
    Blood
  Specific target organ toxicity
  - Single exposure [Category 2]
  ENVIRONMENTAL HAZARDS
  Acute aquatic hazard        Category 2    
    Category 2
  Long-term aquatic hazard
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Danger    
    Harmful if swallowed
  Hazard statements
    Toxic in contact with skin
    Causes eye irritation
    May cause damage to organs : Blood
    Toxic to aquatic life
    Toxic to aquatic life with long lasting effects
  Precautionary statements:
  [Prevention]        Do not breathe dust/fume/gas/mist/vapours/spray.    
    Avoid release to the environment.
    Do not eat, drink or smoke when using this product.
    Wash hands thoroughly after handling.
    Wear protective gloves and eye/face protection.
  1-Naphthylamine

Section 2. HAZARDS IDENTIFICATION
  [Response]        IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.    
    Rinse mouth.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    Remove/Take off immediately all contaminated clothing.
    Wash contaminated clothing before reuse.
    If exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.
    Collect spillage.
  [Storage]        Store locked up.    
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
    1-Naphthylamine
  Components:
  Percent:        >99.0%(GC)(T)    
  CAS Number:        134-32-7    
  Synonyms:        1-Aminonaphthalene    
  Chemical Formula:        C10H9N    

Section 4. FIRST AID MEASURES
    Remove victim to fresh air and keep at rest in a position comfortable for breathing.
  Inhalation:
    Call a POISON CENTER or doctor/physician.
    Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
  Skin contact:
    soap and water. Call a POISON CENTER or doctor/physician.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Call a POISON CENTER or doctor/physician.
  Ingestion:        Call a POISON CENTER or doctor/physician. Rinse mouth.    
  Most important        Cyanosis, Confusion, Dizziness, Headache, Shortness of breath, Weakness,    
  symptoms/effects, acute Nausea, Redness, Pain
  and delayed:
  Protection of first-aiders: A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.
  Indication of immediate Medical ovservation is indicated. Depending on the degree of exposure, periodic
    medical examination is indicated.
  medical attantion and
  special treatment needed, if
  necessary:

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.    
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
    When extinguishing fire, be sure to wear personal protective equipment.
  Special protective
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use extra personal protective equipment (P3 filter respirator for toxic particles). Keep
  Personal precautions,
  protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should
  emergency procedures: be controlled around the leakage area by roping off, etc.
  1-Naphthylamine

Section 6. ACCIDENTAL RELEASE MEASURES
  Environmental precautions: Be careful not to let it flow into rivers, etc., since adverse effects on the environment
    are concerned.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a closed system if possible. Use a local exhaust if dust or aerosol will be
    generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.    
    Store under inert gas.
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
    Light-sensitive, Air-sensitive
    Comply with laws.
  Packaging material:

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.    
  Personal protective equipment
  Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator,
    etc. Use respirators approved under appropriate government standards and follow
    local and national regulations.
    Impervious gloves.
  Hand protection:
  Eye protection:        Safety goggles. A face-shield, if the situation requires.    
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid    
  Form:        Crystal- Powder    
    White - Pale red
  Colour:
  Odour:        Slight Ammoniacal    
  pH: No data available
  Melting point/freezing point:50°C
  Boiling point/range:        301°C    
  Flash point:        No data available    
  Flammability or explosive
  limits:
  Lower:        No data available    
  Upper:        No data available    
  Vapour pressure:        0.53Pa/20°C    
  Vapour density:        4.93    
  Relative density:        No data available    
  Solubility(ies):
  [Water]        Insoluble (1700ppm, 20°C)    
  [Other solvents]
  Very soluble:        Ether, Alcohols    
  Soluble:        Benzene, Dilute acetic acid    
  Log Pow:        2.25    
  Autoignition temperature:        460°C    
  1-Naphthylamine

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.    
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents, Acids, Strong bases
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
  products:

Section 11. TOXICOLOGICAL INFORMATION
    ipr-mus LD50:96 mg/kg
  Acute Toxicity:
    orl-mam LDLo:4 g/kg
    scu-rbt LDLo:300 mg/kg
  Skin corrosion/irritation: No data available
    No data available
  Serious eye
  damage/irritation:
  Germ cell mutagenicity: dns-hmn-fbr 10 mg/L
    mmo-bcs 5 g/L (-S9)
    mmo-sat 10 ug/plate (-S9)
    mmo-sat 50 ug/plate (+S9)
    ipr-rat TDLo:1300 mg/kg/13W-I
  Carcinogenicity:
  IARC =        Group 3 (Not classifiable as carcinogenic to humans)    
  NTP =        No data available    
  Reproductive toxicity:        No data available    
  RTECS Number:        QM1400000    

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        48h LC50:25 ppm (Oryzias latipes)    
    No data available
  Crustacea:
  Algae:        No data available    
  Persistence / degradability: 0 % (by BOD), 3 % (by HPLC)
  Bioaccumulative        13 - 54 (conc. 200 ppb), 9.1 - 27 (conc. 20 ppb)    
  potential(BCF):
  Mobility in soil
  Log Pow:        2.25    
    4.7 x 10-2
  Soil adsorption (Koc):
    2688 - 3777
  Henry's Law
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        6.1: Toxic substance.    
  UN-No:        2077    
    alpha-Naphthylamine
  Proper shipping name:
  Packing group:        III    
    Y
  Marine pollutant

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  The list of a dangerous chemical(2002)/CN-No.: 61830
  1-Naphthylamine


SECTION 16 - ADDITIONAL INFORMATION
N/A

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