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Borane-methyl sulfide complex 13292-87-0 MSDS
Name: Borane-methyl sulfide complex Material Safety Data Sheet
Synonym: BMS, Dimethyl sulfideboran
CAS: 13292-87-0
Section 1 - Chemical Product   MSDS Name:Borane-methyl sulfide complex Material Safety Data Sheet
Synonym:BMS, Dimethyl sulfideboran

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
13292-87-0 Borane-methyl sulfide complex >98 % 236-313-6
Hazard Symbols: XI F
Risk Phrases: 11 15 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Contact with water liberates extremely flammable gases. Irritating to eyes, respiratory system and skin.Water-reactive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver damage. May cause headache.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Reacts violently with water giving off flammable gas which may explode. Will burn if involved in a fire.
Extinguishing Media:
Use dry chemical.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not allow water to get into the container because of violent reaction. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Refrigerator/flammables.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Exposure Limits CAS# 13292-87-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: Clear
Odor: Stench.
pH: Not available.
Vapor Pressure: 54.75 mm Hg @ 4
Viscosity: Not available.
Boiling Point: 44 deg C @ 760.00mm Hg
Freezing/Melting Point: -27 deg C
Autoignition Temperature: Not available.
Flash Point: 18 deg C ( 64.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .7900g/cm3
Molecular Formula: C2H9BS
Molecular Weight: 75.95

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources, contact with water, excess heat.
Incompatibilities with Other Materials:
Acids; acid chlorides; acid anhydrides; oxidizing agents; alcohols; and water.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide, oxides of boron, borane.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 13292-87-0: PV5080000 LD50/LC50:
CAS# 13292-87-0: Draize test, rabbit, eye: 100 mg Severe.
Carcinogenicity:
Borane-methyl sulfide complex - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ORGANOMETALLIC COMPOUND, WATER-REACTIVE, FLAMMABLE
, N.O.S.*
Hazard Class: 4.3 (3)
UN Number: 3207
Packing Group: III
IMO
Shipping Name: ORGANOMETALLIC COMPOUND, WATER-REACTIVE, FLAMMABLE
, N.O.S.
Hazard Class: 4.3 (3)
UN Number: 3207
Packing Group: III
RID/ADR
Shipping Name: ORGANOMETALLIC COMPOUND, WATER-REACTIVE, FLAMMABLE
, N.O.S.
Hazard Class: 4.3
UN Number: 3207
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 15 Contact with water liberates extremely
flammable gases.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 13292-87-0: No information available.
Canada
CAS# 13292-87-0 is listed on Canada's NDSL List.
CAS# 13292-87-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13292-87-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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