Shanghai Yuejiang chemical pro...Purity: 99%Lead Time: 1 Day
Shanghai JunYing Metal Co., Lt...Purity: 96%Lead Time: 14 Day
Hangzhou DayangChem Co., LtdPurity: 98%Lead Time: 7 Day
Henan Tianfu Chemical Co.,LtdPurity: 98%Lead Time: 7 Day
dong shi jie fu zu ran cai li...Purity: 99.8%Lead Time: 3 Day
|Name:||Antimony (III) Oxide P.A. Material Safety Data Sheet|
|Synonym:||Antimonious Oxide; Antimony Peroxide|
Synonym:Antimonious Oxide; Antimony Peroxide
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
|1309-64-4||Antimony trioxide||ca. 100||215-175-0|
Risk Phrases: 40
Section 3 - HAZARDS IDENTIFICATION
Limited evidence of a carcinogenic effect.Cancer suspect agent.
Potential Health Effects
Contact produces irritation, tearing, and burning pain. May cause conjunctivitis.
Causes skin irritation. Repeated or prolonged skin contact may cause antimony measles characterized by itchy papules and pustules around the sweat and fat glands.
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause slow pulse, low blood pressure, bloody stool, shallow breathing, coma, convulsions, and possible death.
Causes respiratory tract irritation. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count.
Possible cancer hazard based on tests with laboratory animals.
Prolonged inhalation may cause respiratory tract inflammation and lung damage. Prolonged or repeated skin contact may cause dermatitis.
May cause chronic heart disease due to effects on the heart muscle.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Antidote: The use of Dimercaprol or BAL (British Anti-Lewisite) as a chelating agent should be determined by qualified medical personnel.
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. May polymerize explosively when involved in a fire. Containers may explode when heated. Combustible material; even though it may take some effort to ignite.
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog or regular foam. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation.
Section 7 - HANDLING and STORAGE
Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep away from heat, sparks and flame. Avoid ingestion and inhalation.
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 1309-64-4: United Kingdom, WEL - TWA: (listed as antimony): 0.5 mg/m3 TWA United Kingdom, WEL - STEL: (listed as antimony): 1.5 mg/m3 STEL United States OSHA: 0.5 mg/m3 TWA (listed under Antimony).
Belgium - TWA: (listed as antimony): 0.5 mg/m3 VLE France - VME: (listed as antimony): 0.5 mg/m3 VME Germany: 0.3 mg/m3 TWA (inhalable fraction, production of diantim trioxide, diantimony Japan: (listed as antimony): 0.1 mg/m3 OEL Malaysia: (listed as antimony): 0.5 mg/m3 TWA Netherlands: (listed as antimony): 0.5 mg/m3 MAC Russia: 1 mg/m3 TWA Russia: (listed as antimony): 0.2 mg/m3 STEL Spain: (listed as antimony): 0.5 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Vapor Pressure: 1 mm Hg @ 574 C
Viscosity: Not available.
Boiling Point: 1822 deg F
Freezing/Melting Point: 1213 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: 5.2
Molecular Formula: Sb2O3
Molecular Weight: 291.4182
Section 10 - STABILITY AND REACTIVITY
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess heat.
Incompatibilities with Other Materials:
Incompatible with bromine trifluoride, acid, oxidizers, halogenated agents, and chlorinated rubber at high temperatures.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, antimony/antimony oxides.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 1309-64-4: CC5650000 CC5720000 LD50/LC50:
CAS# 1309-64-4: Draize test, rabbit, eye: 100 mg Mild; Oral, rat: LD50 = >34600 mg/kg.
Antimony trioxide - ACGIH: A2 - Suspected Human Carcinogen (production) California: carcinogen, initial date 10/1/90 IARC: Group 2B carcinogen Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Fish: Fathead Minnow: 833mg/l; 96H; Not specifiedFish: Bluegill/Sunfish: 530mg/l; 96H; Not specified.96 Hour LD50 bluegill sunfish: >530 mg/L. 96 Hour LD50 fathead minnow: >833 mg/L.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Not regulated as a hazardous material.
Not regulated as a hazardous material.
Shipping Name: ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 1549
Packing group: III
USA RQ: CAS# 1309-64-4: 1000 lb final RQ; 454 kg final RQ
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
R 40 Limited evidence of a carcinogenic effect.
S 22 Do not breathe dust.
S 36 Wear suitable protective clothing.
WGK (Water Danger/Protection)
CAS# 1309-64-4: 2
CAS# 1309-64-4 is listed on Canada's DSL List.
CAS# 1309-64-4 is listed on Canada's Ingredient Disclosure List.
CAS# 1309-64-4 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION