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Hexamethylene diacrylate 13048-33-4 MSDS

SECTION 1: Identification of the substance/mixture and of the company/undertaking
  Product identifiers
    Product name        : 1,6-Hexanediol diacrylate    
    REACH No.        : A registration number is not available for this substance as the substance    
    or its uses are exempted from registration, the annual tonnage does not
    require a registration or the registration is envisaged for a later
    registration deadline.
    CAS-No.        : 13048-33-4    
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances    

SECTION 2: Hazards identification
  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008
    Skin irritation (Category 2), H315
    Eye irritation (Category 2), H319
    Skin sensitisation (Category 1), H317
    For the full text of the H-Statements mentioned in this Section, see Section 16.
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    Xi Irritant        R36/38    
    For the full text of the R-phrases mentioned in this Section, see Section 16.
  Label elements
  Labelling according Regulation (EC) No 1272/2008
    Signal word        Warning    
    Hazard statement(s)
    H315        Causes skin irritation.    
    H317        May cause an allergic skin reaction.    
    H319        Causes serious eye irritation.    
    Precautionary statement(s)
    P280        Wear protective gloves.    
    P305 + P351 + P338        IF IN EYES: Rinse cautiously with water for several minutes. Remove    
    contact lenses, if present and easy to do. Continue rinsing.
    Supplemental Hazard        none    
  Other hazards
    This substance/mixture contains no components considered to be either persistent, bioaccumulative and
    toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients
    Synonyms        : HDODA    
    Formula        : C12H18O4    
    Molecular weight        : 226,27 g/mol    
    CAS-No.        : 13048-33-4    
    EC-No.        : 235-921-9    
    Index-No.        : 607-109-00-8    
  Hazardous ingredients according to Regulation (EC) No 1272/2008
    Component        Classification        Concentration    
  Hexamethylene diacrylate
    CAS-No.        13048-33-4        Skin Irrit. 2; Eye Irrit. 2; Skin        <= 100 %    
    EC-No.        235-921-9        Sens. 1; H315, H317, H319    
    Index-No.        607-109-00-8    
  Hazardous ingredients according to Directive 1999/45/EC
    Component        Classification        Concentration    
  Hexamethylene diacrylate
    CAS-No.        13048-33-4        Xi, R36/38 - R43        <= 100 %    
    EC-No.        235-921-9    
    Index-No.        607-109-00-8    
    For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures
  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
  In case of eye contact
    Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
  If swallowed
    Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
    The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
    section 11
  Indication of any immediate medical attention and special treatment needed
    No data available

SECTION 5: Firefighting measures
  Extinguishing media
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special hazards arising from the substance or mixture
    Carbon oxides
  Advice for firefighters
    Wear self-contained breathing apparatus for firefighting if necessary.
  Further information
    No data available

SECTION 6: Accidental release measures
  Personal precautions, protective equipment and emergency procedures
    Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
    For personal protection see section 8.
  Environmental precautions
    Do not let product enter drains.
  Methods and materials for containment and cleaning up
    Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
    containers for disposal.
  Reference to other sections
    For disposal see section 13.

SECTION 7: Handling and storage
  Precautions for safe handling
    Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
    For precautions see section 2.2.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
    Light sensitive.
    Storage class (TRGS 510): Combustible liquids
  Specific end use(s)
    Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection
  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
    at the end of workday.
  Personal protective equipment
  Eye/face protection
    Face shield and safety glasses Use equipment for eye protection tested and approved under
    appropriate government standards such as NIOSH (US) or EN 166(EU).
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
    Full contact
    Material: Nitrile rubber
    Minimum layer thickness: 0,4 mm
    Break through time: 480 min
    Material tested:Camatril® (KCL 730 / Z677442, Size M)
    Splash contact
    Material: Nitrile rubber
    Minimum layer thickness: 0,2 mm
    Break through time: 66 min
    Material tested:Dermatril® P (KCL 743 / Z677388, Size M)
    data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300     test method: EN374
    If used in solution, or mixed with other substances, and under conditions which differ from EN 374,
    contact the supplier of the CE approved gloves. This recommendation is advisory only and must
    be evaluated by an industrial hygienist and safety officer familiar with the specific situation of
    anticipated use by our customers. It should not be construed as offering an approval for any
    specific use scenario.
  Body Protection
    Complete suit protecting against chemicals, The type of protective equipment must be selected
    according to the concentration and amount of the dangerous substance at the specific workplace.
  Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
    with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
    to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
    respirator. Use respirators and components tested and approved under appropriate government
    standards such as NIOSH (US) or CEN (EU).
  Control of environmental exposure
    Do not let product enter drains.

SECTION 9: Physical and chemical properties
  Information on basic physical and chemical properties
    a) Appearance        Form: liquid    
    Colour: colourless
    b) Odour        No data available    
    c) Odour Threshold        No data available    
    d) pH        No data available    
    e) Melting point/freezing        Melting point/freezing point: 5 °C    
    f) Initial boiling point and 107 °C at 0,3 hPa
    boiling range
    g) Flash point        113 °C - closed cup    
    h) Evaporation rate        No data available    
    i) Flammability (solid, gas) No data available
    j) Upper/lower        No data available    
    flammability or
    explosive limits
    k) Vapour pressure        < 0,01 hPa at 20 °C    
    l) Vapour density        7,81 - (Air = 1.0)    
    m) Relative density        1,01 g/cm3 at 25 °C    
    n) Water solubility        0,36 g/l at 20 °C - slightly soluble    
    o) Partition coefficient: n- log Pow: 2,81 at 25 °C
    p) Auto-ignition        235 °C at 1.013,25 hPa    
    q) Decomposition        No data available    
    r) Viscosity        No data available    
    s) Explosive properties        No data available    
    t) Oxidizing properties        No data available    
  Other safety information
    Relative vapour density 7,81 - (Air = 1.0)

SECTION 10: Stability and reactivity
    No data available
  Chemical stability
    Stable under recommended storage conditions.
  Possibility of hazardous reactions
    No data available
  Conditions to avoid
    Keep away from direct sunlight.
  Incompatible materials
    Oxidizing agentsStrong bases, Strong oxidizing agents, Peroxides, Copper, Iron oxides
  Hazardous decomposition products
    Other decomposition products - No data available
    In the event of fire: see section 5

SECTION 11: Toxicological information
  Information on toxicological effects
  Acute toxicity
    LD50 Oral - Rat - 5.000 mg/kg
    LC0 Inhalation - Rat - male and female - 7 h - 0,41 mg/l
    LD50 Dermal - Rabbit - 3.650 mg/kg
    (OECD Test Guideline 402)
  Skin corrosion/irritation
    Skin - Rabbit
    Result: Irritating to skin. - 4 h
    (OECD Test Guideline 404)
  Serious eye damage/eye irritation
    No data available
  Respiratory or skin sensitisation
    Maximisation Test (GPMT) - Guinea pig
    Result: May cause sensitisation by skin contact.
    (OECD Test Guideline 406)
  Germ cell mutagenicity
    Result: negative
    IARC:        No component of this product present at levels greater than or equal to 0.1% is identified as    
    probable, possible or confirmed human carcinogen by IARC.
  Reproductive toxicity
    No data available
  Specific target organ toxicity - single exposure
    No data available
  Specific target organ toxicity - repeated exposure
    No data available
  Aspiration hazard
    No data available
  Additional Information
    Repeated dose toxicity - Rat - male and female - Oral - No observed adverse effect level - 250 mg/kg
    RTECS: AT1430000
    burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, To the
    best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

SECTION 12: Ecological information
    Toxicity to fish        static test LC50 - Leuciscus idus (Golden orfe) - 4,6 - 10 mg/l - 96 h    
    (DIN 38412)
    Toxicity to daphnia and static test EC50 - Daphnia magna (Water flea) - 2,6 mg/l - 48 h
    other aquatic
    Toxicity to algae        static test EC50 - Desmodesmus subspicatus (Scenedesmus subspicatus) - 1,5    
    mg/l - 72 h
    Toxicity to bacteria        Respiration inhibition EC50 - Sludge Treatment - ca. 270 mg/l - 30 min    
    (OECD Test Guideline 209)
  Persistence and degradability
    Biodegradability        aerobic - Exposure time 28 d    
    Result: 60 - 70 % - Readily biodegradable.
    (OECD Test Guideline 310)
  Bioaccumulative potential
    No data available
  Mobility in soil
    No data available
  Results of PBT and vPvB assessment
    This substance/mixture contains no components considered to be either persistent, bioaccumulative and
    toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
  Other adverse effects
    No data available

SECTION 13: Disposal considerations
  Waste treatment methods
    Offer surplus and non-recyclable solutions to a licensed disposal company.
  Contaminated packaging
    Dispose of as unused product.

SECTION 14: Transport information
  UN number
    ADR/RID: -        IMDG: -        IATA: -    
  UN proper shipping name
    ADR/RID: Not dangerous goods
    IMDG: Not dangerous goods
    IATA:        Not dangerous goods    
  Transport hazard class(es)
    ADR/RID: -        IMDG: -        IATA: -    
  Packaging group
    ADR/RID: -        IMDG: -        IATA: -    
  Environmental hazards
    ADR/RID: no        IMDG Marine pollutant: no        IATA: no    
  Special precautions for user
    No data available

SECTION 15: Regulatory information
    This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
  Safety, health and environmental regulations/legislation specific for the substance or mixture
    No data available
  Chemical Safety Assessment
    For this product a chemical safety assessment was not carried out

SECTION 16: Other information
  Full text of H-Statements referred to under sections 2 and 3.
    Eye Irrit.        Eye irritation    
    H315        Causes skin irritation.    
    H317        May cause an allergic skin reaction.    
    H319        Causes serious eye irritation.    
    Skin Irrit.        Skin irritation    
    Skin Sens.        Skin sensitisation    
  Full text of R-phrases referred to under sections 2 and 3
    Xi        Irritant    
    R36/38        Irritating to eyes and skin.    
    R43        May cause sensitisation by skin contact.    
  Further information
    Copyright 2014 Co. LLC. License granted to make unlimited paper copies for internal use
    The above information is believed to be correct but does not purport to be all inclusive and shall be
    used only as a guide. The information in this document is based on the present state of our knowledge
    and is applicable to the product with regard to appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Corporation and its Affiliates shall not be held
    liable for any damage resulting from handling or from contact with the above product. See
     and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

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