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|Name:||Nitromethane-d3 packaged in 1.00 ml ampules 99 atom % D Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
|13031-32-8||Nitromethane-d3, packaged in 1.00 ml a||235-892-2|
Risk Phrases: 10 22 5
Section 3 - HAZARDS IDENTIFICATION
Flammable. Harmful if swallowed. Heating may cause an explosion.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
May cause eye irritation. Vapors may cause eye irritation. Causes redness and pain.
Exposure may cause irritation characterized by redness, dryness, and inflammation. Causes redness and pain.
Harmful if swallowed. May cause central nervous system depression, kidney damage, and liver damage. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
May cause respiratory tract irritation. May cause effects similar to those described for ingestion. May cause pulmonary edema and severe respiratory disturbances.
Prolonged or repeated skin contact may cause dermatitis. Absorption into the body leads to the formation of methemoglobin which in sufficient concentrations causes cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood).
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Possible aspiration hazard. Get medical aid immediately.
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Flammable liquid and vapor.
For large fires, use water spray, fog, or alcohol-resistant foam.
Use water spray to cool fire-exposed containers. Do NOT use dry chemical.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
Section 7 - HANDLING and STORAGE
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 13031-32-8: Personal Protective Equipment Eyes: Not available.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 100 deg C @ 760.00m
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 35 deg C ( 95.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Solubility in water:
Specific Gravity/Density: 1.1830g/cm3
Molecular Formula: CD3NO2
Molecular Weight: 64.06
Section 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures. Substance is shock sensitive and thermally unstable. Substance forms an explosive sodium salt which bursts into flame on contact with water.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, strong acids, bases, amines, copper, copper alloys, formaldehyde, nitric acid, sodium hydroxide, sulfuric acid, acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), ketones (e.g. acetone, acetophenone, MEK, MIBK), calcium hypochlorite, lead, acetone, potassium hydroxide, silver nitrate, 1,2-diaminoethane, metal halides, aniline, calcium hydroxide.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 13031-32-8 unlisted.
Nitromethane-d3, packaged in 1.00 ml ampules - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
see Dictionary of Substances and their Effects.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
No information available.
No information available.
No information available.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
R 10 Flammable.
R 22 Harmful if swallowed.
R 5 Heating may cause an explosion.
S 41 In case of fire and/or explosion do not breathe
WGK (Water Danger/Protection)
CAS# 13031-32-8: No information available.
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13031-32-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 13031-32-8 is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION