|Name:||Tributyl Phosphate 99% Material Safety Data Sheet|
|Synonym:||TBP, Phosphoric Acid Tributyl Ester, N-Butyl Phosphat|
Synonym:TBP, Phosphoric Acid Tributyl Ester, N-Butyl Phosphat
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22
Section 3 - HAZARDS IDENTIFICATION
Harmful if swallowed.
Potential Health Effects
Causes eye irritation.
Causes skin irritation.
May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea.
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause adverse central nervous system effects including headache, convulsions, and possible death.
May cause paralysis.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Get medical aid immediately. Wash clothing before reuse. Flush skin with plenty of soap and water.
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Provide ventilation.
Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Store in a cool, dry place. Keep from contact with oxidizing materials. Keep away from reducing agents. Keep containers tightly closed.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: clear, colorless
pH: Not available.
Vapor Pressure: < .1 mbar @ 20 deg C
Viscosity: 3.5 cP@25 deg C
Boiling Point: 180-183 deg C
Freezing/Melting Point: <-80 deg C
Autoignition Temperature: > 482 deg C (> 899.60 deg F)
Flash Point: 146 deg C ( 294.80 deg F)
Explosion Limits, lower: None found.
Explosion Limits, upper: None found.
Decomposition Temperature: 280 deg C
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: .9790
Molecular Formula: C12H27O4P
Molecular Weight: 266.1604
Section 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatibilities with Other Materials:
Strong oxidizing agents, alkalis, moisture, water.
Hazardous Decomposition Products:
Phosphine, carbon monoxide, oxides of phosphorus, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 126-73-8: TC7700000 LD50/LC50:
CAS# 126-73-8: Draize test, rabbit, eye: 500 mg Severe; Inhalation, mouse: LC50 = 1300 mg/m3; Inhalation, rat: LC50 = 28 gm/m3/1H; Oral, mouse: LD50 = 1189 mg/kg; Oral, rat: LD50 = 3 gm/kg; Skin, rabbit: LD50 = >3100 mg/kg.
Tributyl phosphate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Fish: Rainbow trout: LC50 = 5.0-9.0 mg/L; 96 Hr.; UnspecifiedFish: Carp: LC50 = 5.0-9.0 mg/L; 96 Hr.; Unspecified
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Not regulated as a hazardous material.
Not regulated as a hazardous material.
Shipping Name: Not regulated.
Dangerous Goods Code:
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
R 22 Harmful if swallowed.
S 25 Avoid contact with eyes.
WGK (Water Danger/Protection)
CAS# 126-73-8: 2
United Kingdom Occupational Exposure Limits
CAS# 126-73-8: OES-United Kingdom, TWA 5 mg/m3 TWA
CAS# 126-73-8: OES-United Kingdom, STEL 5 mg/m3 STEL
CAS# 126-73-8 is listed on Canada's DSL List.
CAS# 126-73-8 is listed on Canada's Ingredient Disclosure List.
CAS# 126-73-8: OEL-AUSTRALIA:TWA 0.2 ppm (2.5 mg/m3)
OEL-BELGIUM:TWA 0.2 ppm (2.2 mg/m3)
OEL-DENMARK:TWA 0.2 ppm (2.5 mg/m3)
OEL-FINLAND:TWA 5 mg/m3;STEL 10 mg/m3;Skin
OEL-FRANCE:TWA 0.2 ppm (2.5 mg/m3)
OEL-THE NETHERLANDS:TWA 5 mg/m3
OEL-THE PHILIPPINES:TWA 5 mg/m3
OEL-RUSSIA:STEL 0.5 mg/m3;Skin
OEL-SWITZERLAND:TWA 0.2 ppm (2.5 mg/m3)
OEL-UNITED KINGDOM:TWA 5 mg/m3;STEL 5 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 126-73-8 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION