isoamyl acetate 123-92-2 MSDS
Name: Isoamyl acetate Material Safety Data Sheet
Synonym: Banana oil; Isoamyl ethanoate; Isopentyl acetate; 3-Methylbutyl acetate; Pear oil
CAS: 123-92-2
Section 1 - Chemical Product   MSDS Name:Isoamyl acetate Material Safety Data Sheet
Synonym:Banana oil; Isoamyl ethanoate; Isopentyl acetate; 3-Methylbutyl acetate; Pear oil

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
123-92-2 Isoamyl acetate >98 204-662-3
Hazard Symbols: None Listed.
Risk Phrases: 10 66

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Repeated exposure may cause skin dryness or cracking.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. Repeated or prolonged exposure may cause drying and cracking of the skin. Not expected to cause an allergic skin reaction.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Prolonged exposure may result in dizziness and general weakness.
Chronic:
Prolonged exposure may produce a narcotic effect.

Section 4 - FIRST AID MEASURES
  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame. Avoid breathing vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry place.
Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 123-92-2: United States OSHA: 100 ppm TWA; 525 mg/m3 TWA Belgium - TWA: 50 ppm VLE; 270 mg/m3 VLE Belgium - STEL: 100 ppm VLE; 540 mg/m3 VLE France - VME: 100 ppm VME; 525 mg/m3 VME Germany: 50 ppm TWA; 270 mg/m3 TWA Japan: 100 ppm OEL; 530 mg/m3 OEL Malaysia: 100 ppm TWA; 532 mg/m3 TWA Netherlands: 100 ppm STEL; 530 mg/m3 STEL Spain: 50 ppm VLA-ED; 270 mg/m3 VLA-ED Spain: 100 ppm VLA-EC; 540 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: odor of pears - banana-like
pH: neutral
Vapor Pressure: 4 mm Hg @ 20 deg C
Viscosity: 1.030 cP @ 9 deg C
Boiling Point: 142 deg C @ 756 mm Hg
Freezing/Melting Point: -78 deg C
Autoignition Temperature: 360 deg C ( 680.00 deg F)
Flash Point: 25 deg C ( 77.00 deg F)
Explosion Limits, lower: 1%
Explosion Limits, upper: 7.5%
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.875 @ 15C
Molecular Formula: C7H14O2
Molecular Weight: 130.19

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, strong bases, nitrates.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 123-92-2: NS9800000 LD50/LC50:
CAS# 123-92-2: Oral, rabbit: LD50 = 7422 mg/kg; Oral, rat: LD50 = 16600 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
Carcinogenicity:
Isoamyl acetate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: AMYL ACETATES
Hazard Class: 3
UN Number: 1104
Packing Group: III
IMO
Shipping Name: AMYL ACETATES
Hazard Class: 3.3
UN Number: 1104
Packing Group: III
RID/ADR
Shipping Name: AMYL ACETATES
Hazard Class: 3
UN Number: 1104
Packing group: III
USA RQ: CAS# 123-92-2: 5000 lb final RQ (Listed under Amyl acetate); 2270 kg fin

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
R 66 Repeated exposure may cause skin dryness or
cracking.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
WGK (Water Danger/Protection)
CAS# 123-92-2: 1
Canada
CAS# 123-92-2 is listed on Canada's DSL List.
CAS# 123-92-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 123-92-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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