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Glycidyl phenyl ether
CAS No.: 122-60-1
Synonyms:
Formula: C9H10O2
Exact Mass: 150.06800
Molecular Weight: 150.17400
PSA: 21.76000
LogP: 1.46420
Reference Price: $6,435/ton Inquiry Now
Glycidyl phenyl ether 122-60-1 MSDS
Name: Glycidyl phenyl ether 99% Material Safety Data Sheet
Synonym: 2,3-Epoxypropylphenylether; 1,2-Epoxy-3-phenoxypropane
CAS: 122-60-1
Section 1 - Chemical Product   MSDS Name:Glycidyl phenyl ether 99% Material Safety Data Sheet
Synonym:2,3-Epoxypropylphenylether; 1,2-Epoxy-3-phenoxypropane

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
122-60-1 Glycidyl phenyl ether 99 204-557-2
Hazard Symbols: T
Risk Phrases: 37/38 43 45 20 52/53

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to respiratory system and skin. May cause sensitization by skin contact. May cause cancer. Harmful by inhalation. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Cancer suspect agent.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
May be harmful if absorbed through the skin.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema. Harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. May cause cancer according to animal studies. Cancer suspect agent.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Keep container closed when not in use. Deep freeze (below -20C).

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 122-60-1: United States OSHA: 10 ppm TWA; 60 mg/m3 TWA Belgium - TWA: 0.1 ppm VLE; 0.6 mg/m3 VLE France - VME: 1 ppm VME; 6 mg/m3 VME Malaysia: 0.1 ppm TWA; 0.6 mg/m3 TWA Netherlands: 0.1 ppm MAC; 0.6 mg/m3 MAC Spain: 0.1 ppm VLA-ED; 0.62 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 11.4 hPa @ 120
Viscosity: 7 MPA 20.00 deg C
Boiling Point: 245 deg C @ 760.00mm Hg
Freezing/Melting Point: 3.5 deg C
Autoignition Temperature: Not available.
Flash Point: 115 deg C ( 239.00 deg F)
Explosion Limits, lower: 1.10 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature:
Solubility in water: 2.4 g/l (20 c)
Specific Gravity/Density: 1.1080g/cm3
Molecular Formula: C9H10O2
Molecular Weight: 150.18

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, acids, bases, amines.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 122-60-1: TZ3675000 LD50/LC50:
CAS# 122-60-1: Draize test, rabbit, eye: 111 mg Mild; Draize test, rabbit, eye: 250 ug/24H Severe; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = >100 ppm/4H; Inhalation, rat: LC50 = >100 ppm/8H; Oral, mouse: LD50 = 1400 mg/kg; Oral, rat: LD50 = 3850 mg/kg; Skin, rabbit: LD50 = 1500 uL/kg.
Oral, mouse LD50: 1400 mg/kg mg/kg LC50: >100ppm/8H Carcinogenicity:
Glycidyl phenyl ether - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 10/1/90 IARC: Group 2B carcinogen Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Goldfish: LC50 = 43 mg/L; 96 Hr.; Modified ASTMD1345

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 20 Harmful by inhalation.
R 37/38 Irritating to respiratory system and skin.
R 43 May cause sensitization by skin contact.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 122-60-1: 2
Canada
CAS# 122-60-1 is listed on Canada's DSL List.
CAS# 122-60-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 122-60-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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