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CAS No.: 12122-67-7
Formula: C4H6N2S4Zn
Exact Mass: 273.87100
Molecular Weight: 275.74400
PSA: 88.24000
LogP: 0.60850
Reference Price: $1,138/kg Inquiry Now
zineb 12122-67-7 MSDS

SECTION 1: Identification of the substance/mixture and of the company/undertaking
  Product identifiers
    Product name        : Zineb    
    REACH No.        : A registration number is not available for this substance as the substance    
    or its uses are exempted from registration, the annual tonnage does not
    require a registration or the registration is envisaged for a later
    registration deadline.
    CAS-No.        : 12122-67-7    
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances    

SECTION 2: Hazards identification
  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008
    Specific target organ toxicity - single exposure (Category 3), H335
    Skin sensitisation (Category 1), H317
    For the full text of the H-Statements mentioned in this Section, see Section 16.
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    Xi Irritant        R37    
    For the full text of the R-phrases mentioned in this Section, see Section 16.
  Label elements
  Labelling according Regulation (EC) No 1272/2008
    Signal word        Warning    
    Hazard statement(s)
    H317        May cause an allergic skin reaction.    
    H335        May cause respiratory irritation.    
    Precautionary statement(s)
    P261        Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.    
    P280        Wear protective gloves.    
    Supplemental Hazard        none    
  Other hazards - none

SECTION 3: Composition/information on ingredients
    Formula        : C4H6N2S4Zn    
    Molecular Weight        : 275,75 g/mol    
    CAS-No.        : 12122-67-7    
    EC-No.        : 235-180-1    
  Hazardous ingredients according to Regulation (EC) No 1272/2008
    Component        Classification        Concentration    
    Skin Sens. 1; STOT SE 3;        -    
    H317, H335
    For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures
  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
  In case of eye contact
    Flush eyes with water as a precaution.
  If swallowed
    Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
    The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
    section 11
  Indication of any immediate medical attention and special treatment needed
    no data available

SECTION 5: Firefighting measures
  Extinguishing media
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special hazards arising from the substance or mixture
    Carbon oxides, nitrogen oxides (NOx), Sulphur oxides, Zinc/zinc oxides
    Carbon oxides, nitrogen oxides (NOx), Sulphur oxides, Zinc/zinc oxides
    Nature of decomposition products not known.
  Advice for firefighters
    Wear self contained breathing apparatus for fire fighting if necessary.
  Further information
    no data available

SECTION 6: Accidental release measures
  Personal precautions, protective equipment and emergency procedures
    Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
    adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
    For personal protection see section 8.
  Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
    environment must be avoided.
  Methods and materials for containment and cleaning up
    Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
    containers for disposal.
  Reference to other sections
    For disposal see section 13.

SECTION 7: Handling and storage
  Precautions for safe handling
    Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
    Provide appropriate exhaust ventilation at places where dust is formed.
    For precautions see section 2.2.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
    Heat-, light-, and moisture-sensitive.
  Specific end use(s)
    A part from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection
  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
    at the end of workday.
  Personal protective equipment
  Eye/face protection
    Face shield and safety glasses Use equipment for eye protection tested and approved under
    appropriate government standards such as NIOSH (US) or EN 166(EU).
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
  Body Protection
    Complete suit protecting against chemicals, The type of protective equipment must be selected
    according to the concentration and amount of the dangerous substance at the specific workplace.
  Respiratory protection
    For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
    level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
    Use respirators and components tested and approved under appropriate government standards
    such as NIOSH (US) or CEN (EU).
  Control of environmental exposure
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
    the environment must be avoided.

SECTION 9: Physical and chemical properties
  Information on basic physical and chemical properties
    a) Appearance        Form: crystalline    
    Colour: yellow
    b) Odour        no data available    
    c) Odour Threshold        no data available    
    d) pH        no data available    
    e) Melting point/freezing        no data available    
    f) Initial boiling point and no data available
    boiling range
    g) Flash point        no data available    
    h) Evapouration rate        no data available    
    i) Flammability (solid, gas) no data available
    j) Upper/lower        no data available    
    flammability or
    explosive limits
    k) Vapour pressure        < 0,001 hPa at 20 °C    
    l) Vapour density        no data available    
    m) Relative density        no data available    
    n) Water solubility        insoluble    
    o) Partition coefficient: n- no data available
    p) Auto-ignition        no data available    
    q) Decomposition        157 °C -    
    r) Viscosity        no data available    
    s) Explosive properties        no data available    
    t) Oxidizing properties        no data available    
  Other safety information
    no data available

SECTION 10: Stability and reactivity
    no data available
  Chemical stability
    Stable under recommended storage conditions.
  Possibility of hazardous reactions
    no data available
  Conditions to avoid
    no data available
  Incompatible materials
    Strong oxidizing agentsStrong oxidizing agents
  Hazardous decomposition products
    Other decomposition products - no data available
    In the event of fire: see section 5

SECTION 11: Toxicological information
  Information on toxicological effects
  Acute toxicity
    LD50 Oral - rat - 1.850 mg/kg
    Remarks: Behavioral:Excitement. Diarrhoea Nutritional and Gross Metabolic:Weight loss or decreased
    weight gain.
    LD50 Oral - rat - female - 8.900 mg/kg
    LD50 Dermal - rat - > 2.500 mg/kg
    LD50 Dermal - rat - > 2.500 mg/kg
  Skin corrosion/irritation
    Skin - rabbit
    Result: No skin irritation
  Serious eye damage/eye irritation
    Eyes - rabbit
    Result: No eye irritation
  Respiratory or skin sensitisation
  Germ cell mutagenicity
    Ames test
    Result: Not mutagenic in Ames Test.
    Other cell types
    DNA inhibition
    Sister chromatid exchange
    DNA inhibition
    Other mutation test systems
    Cytogenetic analysis
    DNA damage
    Cytogenetic analysis
    Carcinogenicity - rat - Oral
    Tumorigenic:Neoplastic by RTECS criteria. Endocrine:Thyroid tumors. Skin and Appendages: Other:
    Carcinogenicity - mouse - Intraperitoneal
    Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Tumorigenic Effects: Uterine tumors. Lungs,
    Thorax, or Respiration:Tumors.
    Carcinogenicity - mouse - Oral
    Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Lungs, Thorax, or Respiration:Tumors.
    Carcinogenicity - rat - Oral
    Tumorigenic:Carcinogenic by RTECS criteria. Gastrointestinal:Tumors.
    Carcinogenicity - rat - Implant
    Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Gastrointestinal:Tumors. Liver:Tumors.
    IARC:        No component of this product present at levels greater than or equal to 0.1% is identified as    
    probable, possible or confirmed human carcinogen by IARC.
  Reproductive toxicity
    Reproductive toxicity - rat - Inhalation
    Effects on Newborn: Growth statistics (e.g., reduced weight gain).
    Reproductive toxicity - rat - Oral
    Maternal Effects: Ovaries, fallopian tubes.
    Reproductive toxicity - rat - Oral
    Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of
    implants). Effects on Fertility: Litter size (e.g.; # fetuses per litter; measured before birth). Effects on
    Embryo or Fetus: Fetal death.
    Developmental Toxicity - rat - Oral
    Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Specific Developmental
    Abnormalities: Central nervous system. Specific Developmental Abnormalities: Musculoskeletal system.
    Developmental Toxicity - rat - Oral
    Specific Developmental Abnormalities: Eye, ear.
  Specific target organ toxicity - single exposure
    May cause respiratory irritation.
  Specific target organ toxicity - repeated exposure
    no data available
  Aspiration hazard
    no data available
  Additional Information
    RTECS: ZH3325000
    Nausea, Dizziness, Headache, Weakness, Convulsions, Unconsciousness, Cough, Breathing difficulties,
    abdominal cramps, Diarrhoea, Eczema, To the best of our knowledge, the chemical, physical, and
    toxicological properties have not been thoroughly investigated.

SECTION 12: Ecological information
    Toxicity to fish        LC50 - Lepomis macrochirus (Bluegill) - > 180 mg/l - 96 h    
    Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - 0,6 - 1,8 mg/l - 48 h
    other aquatic
  Persistence and degradability
  Bioaccumulative potential
    Bioaccumulation        Oncorhynchus mykiss (rainbow trout) - 96 h    
    - 225 µg/l
    Bioconcentration factor (BCF): 770
  Mobility in soil
    no data available
  Results of PBT and vPvB assessment
    PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
  Other adverse effects
    Very toxic to aquatic life with long lasting effects.
    no data available

SECTION 13: Disposal considerations
  Waste treatment methods
    Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
  Contaminated packaging
    Dispose of as unused product.

SECTION 14: Transport information
  UN number
    ADR/RID: 3077        IMDG: 3077        IATA: 3077    
  UN proper shipping name
    IATA:        Environmentally hazardous substance, solid, n.o.s. (Zineb)    
  Transport hazard class(es)
    ADR/RID: 9        IMDG: 9        IATA: 9    
  Packaging group
    ADR/RID: III        IMDG: III        IATA: III    
  Environmental hazards
    ADR/RID: yes        IMDG Marine pollutant: yes        IATA: yes    
  Special precautions for user
  Further information
    EHS-Mark required (ADR, IMDG code 2.10.3) for single packagings and combination
    packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.



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