4-Chloro-3-nitrobenzotrifluoride 121-17-5 MSDS
Name: 4-Chloro-3-nitrobenzotrifluoride 98% Material Safety Data Sheet
Synonym: 4-Chloro-3-nitro-alpha1,alpha1,alpha1-trifluorotoluen
CAS: 121-17-5
Section 1 - Chemical Product   MSDS Name:4-Chloro-3-nitrobenzotrifluoride 98% Material Safety Data Sheet
Synonym:4-Chloro-3-nitro-alpha1,alpha1,alpha1-trifluorotoluen

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
121-17-5 4-Chloro-3-nitrobenzotrifluoride 98% 204-451-6
Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.Harmful.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause nausea and vomiting. May cause unconsciousness.
Inhalation:
Harmful if inhaled. May cause cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood).
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 121-17-5: United States OSHA: 2.5 mg/m3 TWA (as F) (listed under Fluorides Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: .05 hPa @ 20 deg C
Viscosity: Not available.
Boiling Point: 222 deg C @ 760.00mm Hg
Freezing/Melting Point: -2 deg C
Autoignition Temperature: > 450 deg C (> 842.00 deg F)
Flash Point: 101 deg C ( 213.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: IN WATER: 660 MG/L (20C)
Specific Gravity/Density: 1.5110g/cm3
Molecular Formula: C7H3ClF3NO2
Molecular Weight: 225.55

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong bases, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 121-17-5: XS9140000 LD50/LC50:
CAS# 121-17-5: Draize test, rabbit, eye: 100 uL Mild; Oral, mouse: LD50 = 400 mg/kg; Oral, rat: LD50 = 1075 mg/kg.
Carcinogenicity:
4-Chloro-3-nitrobenzotrifluoride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: 3-NITRO-4-CHLOROBENZOTRIFLUORIDE
Hazard Class: 6.1
UN Number: 2307
Packing Group: II
IMO
Shipping Name: 3-NITRO-4-CHLOROBENZOTRIFLUORIDE
Hazard Class: 6.1
UN Number: 2307
Packing Group: II
RID/ADR
Shipping Name: 3-NITRO-4-CHLOROBENZOTRIFLUORIDE
Hazard Class: 6.1
UN Number: 2307
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 121-17-5: No information available.
Canada
CAS# 121-17-5 is listed on Canada's NDSL List.
CAS# 121-17-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 121-17-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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