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2,2'-(Phenylimino)diethanol 120-07-0 MSDS
Name: n-Phenyldiethanolamine 90-95% (gc) remainder n-phenylethanolamine Material Safety Data Sheet
Synonym: 2,2'-(Phenylimino)diethanol; PDEA; N,N-Dihydroxyethylaniline
CAS: 120-07-0
Section 1 - Chemical Product   MSDS Name:n-Phenyldiethanolamine 90-95% (gc) remainder n-phenylethanolamine Material Safety Data Sheet
Synonym:2,2'-(Phenylimino)diethanol; PDEA; N,N-Dihydroxyethylaniline

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
120-07-0 N-phenyl diethanolamine 90-95 204-368-5
Hazard Symbols: XN
Risk Phrases: 22 36

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes.Air sensitive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May be fatal if absorbed through the skin.
Ingestion:
May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 120-07-0: CAS# 122-98-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: Not available.
Odor: None reported.
pH: 8.5(2% aqueous sol.)
Vapor Pressure: Not available.
Viscosity: 123 MPA 60.00 deg C
Boiling Point: 228 deg C @ 20.00HPA
Freezing/Melting Point: 56.00 - 58.00 deg C
Autoignition Temperature: 390 deg C ( 734.00 deg F)
Flash Point: 165 deg C ( 329.00 deg F)
Explosion Limits, lower: .70 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature:
Solubility in water: soluble in ethanol and acetone
Specific Gravity/Density:
Molecular Formula: C10H15NO2
Molecular Weight: 181.23

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Acids - acid chlorides - acid anhydrides - oxidizing agents - air - moisture - chloroformates.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 120-07-0: KM2100000 CAS# 122-98-5: KJ7175000 LD50/LC50:
CAS# 120-07-0: Draize test, rabbit, eye: 100 mg Severe; Oral, mouse: LD50 = 360 mg/kg; Oral, rat: LD50 = 980 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 122-98-5: Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 20 mg/24H Moderate; Oral, rat: LD50 = 2230 mg/kg; Skin, rabbit: LD50 = 63 uL/kg.
Carcinogenicity:
N-phenyl diethanolamine - Not listed by ACGIH, IARC, or NTP.
N-phenyl ethanolamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36 Irritating to eyes.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 120-07-0: 2
CAS# 122-98-5: 1
Canada
CAS# 120-07-0 is listed on Canada's DSL List.
CAS# 122-98-5 is listed on Canada's DSL List.
CAS# 120-07-0 is listed on Canada's Ingredient Disclosure List.
CAS# 122-98-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 120-07-0 is listed on the TSCA inventory.
CAS# 122-98-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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