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triphenyl phosphate 115-86-6 MSDS
Name: Triphenyl phosphate Material Safety Data Sheet
Synonym: None
CAS: 115-86-6
Section 1 - Chemical Product   MSDS Name:Triphenyl phosphate Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
115-86-6 Triphenyl phosphate 98-100 204-112-2
Hazard Symbols: N
Risk Phrases: 50/53

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin. May cause an allergic reaction in certain individuals.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
May cause liver and kidney damage.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use carbon dioxide or dry chemical. Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 115-86-6: United Kingdom, WEL - TWA: 3 mg/m3 TWA United Kingdom, WEL - STEL: 6 mg/m3 STEL United States OSHA: 3 mg/m3 TWA Belgium - TWA: 3 mg/m3 VLE France - VME: 3 mg/m3 VME Germany: 3 mg/m3 TWA (inhalable fraction) Malaysia: 3 mg/m3 TWA Netherlands: 3 mg/m3 MAC Russia: 1 mg/m3 TWA Spain: 3 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Flakes
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: 1.3 hPa @ 193 C
Viscosity: Not available.
Boiling Point: 245 deg C
Freezing/Melting Point: 49 deg C
Autoignition Temperature: 500 deg C ( 932.00 deg F)
Flash Point: 428 deg F ( 220.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble in water.
Specific Gravity/Density: 1.3
Molecular Formula: C18 H15 O4 P
Molecular Weight: 326.30

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 115-86-6: TC8400000 LD50/LC50:
CAS# 115-86-6: Dermal, guinea pig: LD50 = >4 gm/kg; Oral, mouse: LD50 = 1320 mg/kg; Oral, rat: LD50 = 3500 mg/kg; Skin, rabbit: LD50 = >7900 mg/kg.
Carcinogenicity:
Triphenyl phosphate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Rainbow trout: LC50 = 0.3 mg/L; 96 Hr.; UnspecifiedFish: Fathead Minnow: LC50 = 0.87 mg/L; 96 Hr.; Flow-throughFish: Bluegill/Sunfish: LC50 = 290.0 mg/L; 96 Hr.; Static ConditionWater flea Daphnia: EC50 = 1.0 mg/L; 48 Hr.; Unspecified

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE
Hazard Class: 9
UN Number: 3077
Packing Group: III
IMO
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE
Hazard Class: 9
UN Number: 3077
Packing Group: III
RID/ADR
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE
Hazard Class: 9
UN Number: 3077
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: N
Risk Phrases:
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 115-86-6: 2
Canada
CAS# 115-86-6 is listed on Canada's DSL List.
CAS# 115-86-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 115-86-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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