|Name:||Geranyl linalool, tech.,ca.95%, mixture of isomers Material Safety Data Sheet|
Synonym: 3,7,11,15-Tetramethyl-1,6,10,14-hexadecatetraene-3-ol; E,E-3,7,11,15-Tetramethyl-1,6,10,14-hexadecatetraen-3-ol
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
|1113-21-9||Geranyl linalool, tech., mixture of is||ca. 95||214-201-8|
Risk Phrases: 38
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to skin. Potential Health Effects
Causes eye irritation. May cause chemical conjunctivitis.
Causes skin irritation.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Effects may be delayed.
SECTION 4 - FIRST AID MEASURES
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
SECTION 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1113-21-9: Personal Protective Equipment
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: clear slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: <1 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 250 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: 250 deg C ( 482.00 deg F)
Flash Point: 160 deg C ( 320.00 deg F)
Explosion Limits, lower: .50 vol %
Explosion Limits, upper: 2.10 vol %
Decomposition Temperature: Not available.
Solubility in water: insoluble
Specific Gravity/Density: .8830g/cm3
Molecular Formula: C20H34O
Molecular Weight: 290.48
SECTION 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants, very acidic or very alkaline substances.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1113-21-9: MM0335000
CAS# 1113-21-9: Draize test, rabbit, eye: 100 mg; Draize test,
rabbit, skin: 500 mg; Oral, rat: LD50 = >5 gm/kg; Skin, rabbit: LD50 = >5 gm/kg.
Geranyl linalool, tech., mixture of isomers - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
SECTION 12 - ECOLOGICAL INFORMATION Other No information available.
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material.
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XI
R 38 Irritating to skin.
WGK (Water Danger/Protection) CAS# 1113-21-9: No information available. Canada CAS# 1113-21-9 is listed on Canada's DSL List. CAS# 1113-21-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1113-21-9 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.
SECTION 16 - ADDITIONAL INFORMATION