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Dibutylamine
CAS No.: 111-92-2
Synonyms:
Formula: C8H19N
Exact Mass: 129.15200
Molecular Weight: 129.24300
PSA: 12.03000
LogP: 2.56710
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Dibutylamine 111-92-2 MSDS
Name: Di-n-Butylamine p.a. Material Safety Data Sheet
Synonym:
CAS: 111-92-2
Section 1 - Chemical Product   MSDS Name:Di-n-Butylamine p.a. Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
111-92-2 Di-(N-Butyl)amine 100 203-921-8
Hazard Symbols: XN
Risk Phrases: 10 20/21/22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if swallowed.Corrosive.
Potential Health Effects
Eye:
May cause 'blue haze' or 'halo vision'. Lachrymator (substance which increases the flow of tears). Causes eye irritation and burns.
Skin:
May be absorbed through the skin in harmful amounts. Causes severe skin irritation and burns.
Ingestion:
Harmful if swallowed. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
Vapors can travel to a source of ignition and flash back. Material will burn in a fire. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Vapors may form an explosive mixture with air.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Contact professional fire-fighters immediately.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat and flame. Store in a tightly closed container.
Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Appearance: clear, colorless
Odor: amine-like odor.
pH: Not available.
Vapor Pressure: 23 mm Hg @ 20 C
Viscosity: 0.9 mPas 20 deg C
Boiling Point: 159 deg C @ 760.00mm Hg
Freezing/Melting Point: -62 deg C
Autoignition Temperature: 260 deg C ( 500.00 deg F)
Flash Point: 39 deg C ( 102.20 deg F)
Explosion Limits, lower: .60 vol %
Explosion Limits, upper: 6.80 vol %
Decomposition Temperature:
Solubility in water: IN WATER: 4.05 G/L (25C)
Specific Gravity/Density: .7670g/cm3
Molecular Formula: C8H19N
Molecular Weight: 129.24

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, carbon dioxide, acids, acid chlorides, halogenated compounds, and acid anhydrides Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, amines.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 111-92-2: HR7780000 LD50/LC50:
CAS# 111-92-2: Oral, mouse: LD50 = 290 mg/kg; Oral, rat: LD50 = 189 mg/kg; Skin, rabbit: LD50 = 1010 uL/kg.
Carcinogenicity:
Di-(N-Butyl)amine - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: DI-n-BUTYLAMINE
Hazard Class: 8
UN Number: 2248
Packing Group: II
IMO
Shipping Name: DI-n-BUTYLAMINE
Hazard Class: 8
UN Number: 2248
Packing Group: II
RID/ADR
Shipping Name: DI-n-BUTYLAMINE
Dangerous Goods Code: 8(54B)
UN Number: 2248

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 111-92-2: 1
United Kingdom Occupational Exposure Limits
Canada
CAS# 111-92-2 is listed on Canada's DSL List.
CAS# 111-92-2 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 111-92-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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