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diethylene glycol monoethyl ether 111-90-0 MSDS
Name: Diethylene Glycol Monoethyl Ether Material Safety Data Sheet
Synonym: 2-(2-Ethoxyethanol)-ethanol; carbitol; carbitol cellosolve; diethylene glycol ether; ethyl carbitol; DGME; ethyl digo
CAS: 111-90-0
Section 1 - Chemical Product   MSDS Name:Diethylene Glycol Monoethyl Ether Material Safety Data Sheet
Synonym:2-(2-Ethoxyethanol)-ethanol; carbitol; carbitol cellosolve; diethylene glycol ether; ethyl carbitol; DGME; ethyl digo

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
111-90-0 Diethylene glycol monoethyl ether 100.0 203-919-7
Hazard Symbols: XI
Risk Phrases: 36

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes.
Potential Health Effects
Eye:
May cause eye irritation. May cause transient corneal injury.
Causes redness and pain.
Skin:
May cause mild skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression. May be harmful if swallowed.
Inhalation:
Low hazard for usual industrial handling. May cause kidney damage.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid.
Notes to Physician:
Monitor kidney function closely.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustible liquid. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Use with adequate ventilation. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Store protected from light. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 111-90-0: Netherlands: 32 ppm MAC; 180 mg/m3 MAC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: mild odor - fruity odor
pH: Not available.
Vapor Pressure: .14 mm Hg @ 20 C
Viscosity: 3.9 cP 25 C
Boiling Point: 396 deg F
Freezing/Melting Point: -134 deg F
Autoignition Temperature: 400 deg F ( 204.44 deg C)
Flash Point: 187 deg F ( 86.11 deg C)
Explosion Limits, lower: 1.2@ 135C
Explosion Limits, upper: 23.5@ 182C
Decomposition Temperature: Not available.
Solubility in water: soluble in water.
Specific Gravity/Density: .9902 @20C
Molecular Formula: C6H14O3
Molecular Weight: 134.0962

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures. Explosive peroxides may form on concentration. Peroxides can be detonated by friction, impact, or heating.
Conditions to Avoid:
Ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, isocyanates.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 111-90-0: KK8750000 LD50/LC50:
CAS# 111-90-0: Dermal, guinea pig: LD50 = >32 gm/kg; Draize test, rabbit, eye: 500 mg Moderate; Draize test, rabbit, eye: 125 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >5240 mg/m3/4H; Oral, mouse: LD50 = 6600 uL/kg; Oral, mouse: LD50 = 7250 mg/kg; Oral, rabbit: LD50 = 3620 mg/kg; Oral, rat: LD50 = 5500 uL/kg; Oral, rat: LD50 = 7500 mg/kg; Skin, rabbit: LD50 = 4200 uL/kg; Skin, rabbit: LD50 = 8.5 ml/kg/2H; Skin, rat: LD50 = 6 mL/kg.
Carcinogenicity:
Diethylene glycol monoethyl ether - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Fathead Minnow: 26.6g/L; 96HFish: Rainbow trout: LC50 = 13,420 mg/L; 96 Hr.; Unspecified conditionsFish: Bluegill/Sunfish: LC50 = 10,000 mg/L; 96 Hr.; Static conditions, 23 degrees CWater flea Daphnia: LC50 = 4026 mg/L; 48 Hr.; Unspecified

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36 Irritating to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 111-90-0: 1
Canada
CAS# 111-90-0 is listed on Canada's DSL List.
CAS# 111-90-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-90-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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