diethylenetriamine 111-40-0 MSDS
Name: Diethylenetriamine Material Safety Data Sheet
Synonym: Aminothylethandiamine; 3-azapentane; bis(B-aminoethyl)amine; D.E.H.; 2,2-diaminodiethylamine; 2,2-ininobisethylamin
CAS: 111-40-0
Section 1 - Chemical Product   MSDS Name:Diethylenetriamine Material Safety Data Sheet
Synonym:Aminothylethandiamine; 3-azapentane; bis(B-aminoethyl)amine; D.E.H.; 2,2-diaminodiethylamine; 2,2-ininobisethylamin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
111-40-0 Diethylene triamine 100.0 203-865-4
Hazard Symbols: C
Risk Phrases: 21/22 34 43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Causes burns. May cause sensitization by skin contact.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May result in corneal injury. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal tract burns. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.
Inhalation:
May cause asthmatic attacks due to allergic sensitization of the respiratory tract. Causes respiratory tract irritation with possible burns.
Chronic:
Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration. Repeated exposure may cause allergic respiratory reaction (asthma).

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Use water spray to dilute spill to a non-flammable mixture. Use water spray to disperse the gas/vapor.
Remove all sources of ignition. Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Keep away from heat and flame. Store in a tightly closed container.
Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Keep away from acids.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 111-40-0: United Kingdom, WEL - TWA: 1 ppm TWA; 4.3 mg/m3 TWA United Kingdom, WEL - STEL: 3 ppm STEL; 12.9 mg/m3 STEL Belgium - TWA: 1 ppm VLE; 4.3 mg/m3 VLE France - VME: 1 ppm VME; 4 mg/m3 VME Malaysia: 1 ppm TWA; 4.2 mg/m3 TWA Netherlands: 1 ppm MAC; 4 mg/m3 MAC Spain: 1 ppm VLA-ED; 4.3 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless to yellow
Odor: amine-like
pH: Strongly alkaline
Vapor Pressure: 0.37 mm Hg @ 20C
Viscosity: 0.0714 Ps 20 C
Boiling Point: 207 deg C
Freezing/Melting Point: -35 deg C
Autoignition Temperature: 395 deg C ( 743.00 deg F)
Flash Point: 102 deg C ( 215.60 deg F)
Explosion Limits, lower: 2.0%
Explosion Limits, upper: 11.6%
Decomposition Temperature: Not available.
Solubility in water: soluble in water.
Specific Gravity/Density: .9586
Molecular Formula: C4H13N3
Molecular Weight: 103.1111

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Corrosive to copper and its alloys, ignites on contact with cellulose nitrate of high surface area, forms a shock-sensitive explosive with nitromethane, and is incompatible with acids, chlorine, halogenated compounds, oxidizing agents and reactive organic compounds.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, amines.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 111-40-0: IE1225000 LD50/LC50:
CAS# 111-40-0: Dermal, guinea pig: LD50 = 170 uL/kg; Draize test, rabbit, skin: 500 mg; Oral, rat: LD50 = 1080 mg/kg; Skin, rabbit: LD50 = 1090 mg/kg.
Carcinogenicity:
Diethylene triamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Water flea Daphnia: EC50 = 330 mg/L; 24 Hr.; Unspecified

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: DIETHYLENETRIAMINE
Hazard Class: 8
UN Number: 2079
Packing Group: II
IMO
Shipping Name: DIETHYLENETRIAMINE
Hazard Class: 8
UN Number: 2079
Packing Group: II
RID/ADR
Shipping Name: DIETHYLENETRIAMINE
Hazard Class: 8
UN Number: 2079
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 111-40-0: 2
Canada
CAS# 111-40-0 is listed on Canada's DSL List.
CAS# 111-40-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-40-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

Home   |   Announcement   |   Partners   |   Business Cooperation   |   Suppliers   |   Products    |   About Us   |   Contact Us   |   Privacy Policy   |   Terms & Conditions   |   Legal Statement

Copyright © 2013-2016 MOLBASE All Rights Reserved ICP Shanghai 14014220