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piperazine 110-85-0 MSDS
Name: Piperazine anhydrous 99% Material Safety Data Sheet
Synonym: Antitren; 1,4-Diethylenediamine; N,N-Diethylenediamine; Hexahydro-1,4-diazine; Piperazidine; Pyrazine hexahydrat
CAS: 110-85-0
Section 1 - Chemical Product   MSDS Name:Piperazine anhydrous 99% Material Safety Data Sheet
Synonym:Antitren; 1,4-Diethylenediamine; N,N-Diethylenediamine; Hexahydro-1,4-diazine; Piperazidine; Pyrazine hexahydrat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
110-85-0 Piperazine, anhydrous 100 203-808-3
Hazard Symbols: C
Risk Phrases: 34 42/43 52/53

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns. May cause sensitization by inhalation and skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Corrosive.Hygroscopic (absorbs moisture from the air).Light sensitive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. Causes chemical burns to the respiratory tract.
Chronic:
Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration. Prolonged or repeated exposure may cause permanent eye damage. Repeated exposure may cause allergic respiratory reaction (asthma).

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Gently lift eyelids and flush continuously with water.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get on skin or in eyes. Do not ingest or inhale.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry place.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 110-85-0: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL Belgium - TWA: 0.1 mg/m3 VLE Belgium - STEL: 0.3 mg/m3 VLE Germany: 0.1 mg/m3 TWA Spain: 0.1 mg/m3 VLA-ED Spain: 0.3 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: Not available.
Odor: Ammonia-like odor.
pH: Not available.
Vapor Pressure: .8 mm Hg
Viscosity: Not available.
Boiling Point: 145.0 - 146.0 deg C @ 760.00mm Hg
Freezing/Melting Point: 108.00 - 110.00 deg C
Autoignition Temperature: 340 deg C ( 644.00 deg F)
Flash Point: 82 deg C ( 179.60 deg F)
Explosion Limits, lower: 4.00 vol %
Explosion Limits, upper: 14.00 vol %
Decomposition Temperature:
Solubility in water: practically insoluble in ether
Specific Gravity/Density:
Molecular Formula: C4H10N2
Molecular Weight: 86.14

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents; strong acids; acid chlorides; acid anhydrides; light; moisture; dicyanofurazan.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 110-85-0: TK7800000 LD50/LC50:
CAS# 110-85-0: Draize test, rabbit, eye: 250 ug Severe; Draize test, rabbit, eye: 250 ug/24H Severe; Inhalation, mouse: LC50 = 5400 mg/m3/2H; Oral, mouse: LD50 = 600 mg/kg; Oral, rat: LD50 = 1900 mg/kg; Skin, rabbit: LD50 = 4 mL/kg.
Carcinogenicity:
Piperazine, anhydrous - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: PIPERAZINE
Hazard Class: 8
UN Number: 2579
Packing Group: III
IMO
Shipping Name: PIPERAZINE, SOLID or SOLUTION
Hazard Class: 8
UN Number: 2579
Packing Group: III
RID/ADR
Shipping Name: PIPERAZINE
Hazard Class: 8
UN Number: 2579
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 42/43 May cause sensitization by inhalation and
skin contact.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 110-85-0: 2
Canada
CAS# 110-85-0 is listed on Canada's DSL List.
CAS# 110-85-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-85-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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