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|Name:||Acetonylacetone 97% Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38
Section 3 - HAZARDS IDENTIFICATION
Irritating to eyes, respiratory system and skin.Combustible liquid.
Potential Health Effects
Causes eye irritation.
Causes skin irritation.
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system effects.
Causes respiratory tract irritation.
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode if exposed to fire.
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Keep away from heat, sparks, and flame. Store in a cool, dry place.
Keep container closed when not in use. Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 110-13-4: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Wear appropriate gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear slight brown
Odor: Not available.
pH: Not available.
Vapor Pressure: 0.57 mbar @ 20
Viscosity: Not available.
Boiling Point: 191 deg C @ 760 mm Hg
Freezing/Melting Point: -6 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: 78 deg C ( 172.40 deg F)
Explosion Limits, lower: 1.50 vol %
Explosion Limits, upper: Not available.
Solubility in water: miscible
Specific Gravity/Density: .9730g/cm3
Molecular Formula: C6H10O2
Molecular Weight: 114.14
Section 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, acids, excess heat.
Incompatibilities with Other Materials:
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 110-13-4: MO3150000 LD50/LC50:
CAS# 110-13-4: Dermal, guinea pig: LD50 = 6.6 mL/kg; Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 100 mg/24H Moderate; Inhalation, rat: LC50 = 2000 ppm/4H; Oral, mouse: LD50 = 2386 mg/kg; Oral, rat: LD50 = 1600 mg/kg.
Acetonylacetone - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Shipping Name: Not regulated.
Shipping Name: Not regulated.
Shipping Name: Not regulated.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
R 36/37/38 Irritating to eyes, respiratory system
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 110-13-4: No information available.
CAS# 110-13-4 is listed on Canada's DSL List.
CAS# 110-13-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 110-13-4 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION