propyl acetate 109-60-4 MSDS
Name: Propyl Acetate (Pract) 90% (GC) Material Safety Data Sheet
Synonym: Acetic Acid N-Propyl Ester; 1-Propyl Acetate
CAS: 109-60-4
Section 1 - Chemical Product   MSDS Name:Propyl Acetate (Pract) 90% (GC) Material Safety Data Sheet
Synonym:Acetic Acid N-Propyl Ester; 1-Propyl Acetate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
109-60-4 N-Propyl Acetate 90 203-686-1
Hazard Symbols: F
Risk Phrases: 11

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable.Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the flow of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Ingestion of large amounts may cause CNS depression.
Inhalation:
Inhalation of vapor may cause respiratory tract irritation. May cause effects similar to those described for ingestion. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. Can produce delayed pulmonary edema. May cause burning sensation in the chest.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire.
Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. May polymerize explosively when involved in a fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Use dry chemical, carbon dioxide, or alcohol-resistant foam. Do NOT use straight streams of water. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Use with adequate ventilation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Do not store near combustible materials. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 109-60-4: United Kingdom, WEL - TWA: 200 ppm TWA; 849 mg/m3 TWA United Kingdom, WEL - STEL: 250 ppm STEL; 1060 mg/m3 STEL United States OSHA: 200 ppm TWA; 840 mg/m3 TWA Belgium - TWA: 200 ppm VLE; 847 mg/m3 VLE Belgium - STEL: 250 ppm VLE; 1055 mg/m3 VLE France - VME: 200 ppm VME; 840 mg/m3 VME Germany: 100 ppm TWA; 420 mg/m3 TWA Japan: 200 ppm OEL; 830 mg/m3 OEL Malaysia: 200 ppm TWA; 835 mg/m3 TWA Netherlands: 200 ppm STEL; 800 mg/m3 STEL Netherlands: 100 ppm MAC; 420 mg/m3 MAC Russia: 200 mg/m3 TWA Spain: 200 ppm VLA-ED; 849 mg/m3 VLA-ED Spain: 250 ppm VLA-EC; 1060 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: fruity odor
pH: Not available.
Vapor Pressure: 25 mm Hg @25C
Viscosity: Not available.
Boiling Point: 101 deg C
Freezing/Melting Point: -95 deg C
Autoignition Temperature: 450 deg C ( 842.00 deg F)
Flash Point: 14 deg C ( 57.20 deg F)
Explosion Limits, lower: 2.0
Explosion Limits, upper: 8.0
Decomposition Temperature:
Solubility in water: Slightly soluble in water
Specific Gravity/Density: 1.89
Molecular Formula: CH3COOCH2CH2CH3
Molecular Weight: 102.0688

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Alkalies, nitrates, acids, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 109-60-4: AJ3675000 LD50/LC50:
CAS# 109-60-4: Draize test, rabbit, eye: 500 mg/24H Mild; Oral, mouse: LD50 = 8300 mg/kg; Oral, rabbit: LD50 = 6640 mg/kg; Oral, rat: LD50 = 9370 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
Carcinogenicity:
N-Propyl Acetate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Fathead Minnow: 60mg/L; 96H Other For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND EXPOSURE DATA."

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: N-PROPYL ACETATE
Hazard Class: 3
UN Number: 1276
Packing Group: II
IMO
Shipping Name: NORMAL-PROPYL ACETATE
Hazard Class: 3.2
UN Number: 1276
Packing Group: II
RID/ADR
Shipping Name: N-PROPYL ACETATE
Hazard Class: 3
UN Number: 1276
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 109-60-4: 1
Canada
CAS# 109-60-4 is listed on Canada's DSL List.
CAS# 109-60-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-60-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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