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Isobutyl vinyl ether
CAS No.: 109-53-5
Synonyms:
Formula: C6H12O
Exact Mass: 100.08900
Molecular Weight: 100.15900
PSA: 9.23000
LogP: 1.80250
Reference Price: $1,452/ton Inquiry Now
Isobutyl vinyl ether 109-53-5 MSDS
Name: Isobutyl vinyl ether 99.5% (gc) stabilized with 0.1% potassium Material Safety Data Sheet
Synonym: 1-(Ethenyloxy)-2-methylpropan
CAS: 109-53-5
Section 1 - Chemical Product   MSDS Name:Isobutyl vinyl ether 99.5% (gc) stabilized with 0.1% potassium Material Safety Data Sheet
Synonym:1-(Ethenyloxy)-2-methylpropan

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
109-53-5 Isobutyl vinyl ether 99.5 203-678-8
Hazard Symbols: F
Risk Phrases: 11

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Vapors may cause dizziness or suffocation.
Chronic:
None

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Extremely flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 109-53-5: CAS# 1310-58-3: United Kingdom, WEL - STEL: 2 mg/m3 STEL Belgium - STEL: 2 mg/m3 VLE France - VLE: 2 mg/m3 VLE Japan: 2 mg/m3 Ceiling Malaysia: 2 mg/m3 Ceiling Spain: 2 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: Ether-like
pH: Not available.
Vapor Pressure: 89 mbar @20 deg C
Viscosity: 0.476 mPas 5 deg C
Boiling Point: 83 deg C @ 760.00mm Hg
Freezing/Melting Point: -112 deg C
Autoignition Temperature: 195 deg C ( 383.00 deg F)
Flash Point: 15 deg F ( -9.44 deg C)
Explosion Limits, lower: 1.40 vol %
Explosion Limits, upper: 7.80 vol %
Decomposition Temperature:
Solubility in water: 0.7 G/L (25C)
Specific Gravity/Density: .7690g/cm3
Molecular Formula: C6H12O
Molecular Weight: 100.0834

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Isobutyl vinyl ether is incompatible with strong oxidizing agents, and strong acids. Potassium hydroxide is incompatible with acids, amoonia hexachloroplatinate, p-Bis(1,3-dibromoethyl) benzene, bromoform, cyclic polyethylene oxides, chlorine dioxide, cyclopentadiene, germanium, hyponitrous acid, maleic anhydride, nitroalkanes, nitrobenzene, nitrogen trichloride, 2-nitrophenol, potassium peroxodisulfate, sugars, 2,2,3,3-tetrafluoropropanol, tetrahydrofuran, thorium dicarbide, 2,4,6-trinitrotoluene Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 109-53-5: KO1300000 CAS# 1310-58-3: TT2100000 LD50/LC50:
CAS# 109-53-5: Oral, rat: LD50 = 17 mL/kg; Skin, rabbit: LD50 = 20 mL/kg.
CAS# 1310-58-3: Draize test, rabbit, skin: 50 mg/24H Severe; Oral, rat: LD50 = 273 mg/kg.
Carcinogenicity:
Isobutyl vinyl ether - Not listed by ACGIH, IARC, or NTP.
Potassium hydroxide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: VINYL ISOBUTYL ETHER, INHIBITED
Hazard Class: 3
UN Number: 1304
Packing Group: II
IMO
Shipping Name: VINYL ISOBUTYL ETHER, INHIBITED
Hazard Class: 3.2
UN Number: 1304
Packing Group: II
RID/ADR
Shipping Name: VINYL ISOBUTYL ETHER, INHIBITED
Hazard Class: 3
UN Number: 1304
Packing group: II
USA RQ: CAS# 1310-58-3: 1000 lb final RQ; 454 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
WGK (Water Danger/Protection)
CAS# 109-53-5: 1
CAS# 1310-58-3: 1
Canada
CAS# 109-53-5 is listed on Canada's DSL List.
CAS# 1310-58-3 is listed on Canada's DSL List.
CAS# 109-53-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 1310-58-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-53-5 is listed on the TSCA inventory.
CAS# 1310-58-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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