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1-Methoxy-2-propyl acetate 108-65-6 MSDS
Name: 2-(1-Methoxy)propyl Acetate 97% (GC) Material Safety Data Sheet
Synonym: 1-Methoxy-2-Acetoxypropane; 1,2-Propandiol Monomethyl Ether Acetat
CAS: 108-65-6
Section 1 - Chemical Product   MSDS Name:2-(1-Methoxy)propyl Acetate 97% (GC) Material Safety Data Sheet
Synonym:1-Methoxy-2-Acetoxypropane; 1,2-Propandiol Monomethyl Ether Acetat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
108-65-6 2-(1-Methoxy)Proxy Acetate 97% 203-603-9
Hazard Symbols: XI
Risk Phrases: 10 36/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Irritating to eyes and skin.Flammable liquid.
Potential Health Effects
Eye:
Causes mild eye irritation.
Skin:
Causes mild skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Inhalation of vapor may cause respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May be ignited by heat, sparks, and flame. Vapors may form an explosive mixture with air. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water fog, dry chemical, carbon dioxide, or regular foam. Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 108-65-6: United Kingdom, WEL - TWA: 50 ppm TWA; 274 mg/m3 TWA United Kingdom, WEL - STEL: 100 ppm STEL; 548 mg/m3 STEL Belgium - TWA: 50 ppm VLE; 275 mg/m3 VLE Belgium - STEL: 100 ppm VLE; 550 mg/m3 VLE Germany: 50 ppm TWA; 270 mg/m3 TWA Netherlands: 100 ppm MAC; 550 mg/m3 MAC Spain: 50 ppm VLA-ED; 275 mg/m3 VLA-ED Spain: 100 ppm VLA-EC; 550 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: Ethereal odor.
pH: Not available.
Vapor Pressure: 4.9 mbar @ 20 deg C
Viscosity: Not available.
Boiling Point: 146 deg C @ 760.00mm Hg
Freezing/Melting Point: -67 deg C
Autoignition Temperature: 333 deg C ( 631.40 deg F)
Flash Point: 42 deg C ( 107.60 deg F)
Explosion Limits, lower: 1.30 vol %
Explosion Limits, upper: 13.10 vol %
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: .9690g/cm3
Molecular Formula: C6H12O3
Molecular Weight: 132.16

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures. This material may be sensitive to peroxide formation.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents - strong acids - strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 108-65-6: AI8925000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 108-65-6: Oral, rat: LD50 = 8532 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
2-(1-Methoxy)Proxy Acetate - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Static acute LC50 for Fathead Minnow is 161 mg/l. Material is practically non-toxic to fish on an acute basis (LC50>100 mg/l).
Static acute LC50 for daphnids (Daphnia magna) is reported to be 408 mg/L. Material is practically non-toxic to aquatic invertebrates on a static acute basis (LC50>100 mg/l).

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 108-65-6: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 108-65-6 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 108-65-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-65-6 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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