3-Chloroaniline 108-42-9 MSDS
Name: 3-Chloroaniline 99% Material Safety Data Sheet
Synonym: Non
CAS: 108-42-9
Section 1 - Chemical Product   MSDS Name:3-Chloroaniline 99% Material Safety Data Sheet
Synonym:Non

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
108-42-9 3-Chloroaniline 99.0 203-581-0
Hazard Symbols: T C N
Risk Phrases: 33 34 24/25 50/53

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Danger of cumulative effects. Causes burns. Toxic in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Light sensitive.Air sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Substance is rapidly absorbed through the skin.
If absorbed, may cause symptoms similar to those for ingestion.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause liver and kidney damage. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, and death. Methemoglobinemia is characterized by dizziness, drowsiness, headache, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), rapid heart rate and chocolate-brown colored blood. May cause central nervous system effects. May cause discoloration of the lips, tongue, and mucous membranes.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
May cause cancer according to animal studies.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do NOT use straight streams of water.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 108-42-9: Russia: 0.05 mg/m3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.05 mm Hg @20C
Viscosity: Not available.
Boiling Point: 229.8 deg C
Freezing/Melting Point: -10.4 deg C
Autoignition Temperature: 500 deg C ( 932.00 deg F)
Flash Point: 190 deg C ( 374.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 190 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: 1.2060g/cm3
Molecular Formula: C6H6ClN
Molecular Weight: 127.57

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures. Substance may undergo color change upon exposure to light and air.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Acids, acid chlorides, acid anhydrides, strong oxidizing agents, chloroformates.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 108-42-9: BX0350000 LD50/LC50:
CAS# 108-42-9: Dermal, guinea pig: LD50 = 100 mg/kg; Inhalation, mouse: LC50 = 550 mg/m3/4H; Oral, mouse: LD50 = 334 mg/kg; Oral, rat: LD50 = 256 mg/kg; Skin, rat: LD50 = 250 mg/kg.
Oral, guinea pig: LD50 = 200 mg/kg Carcinogenicity:
3-Chloroaniline - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CHLOROANILINES, LIQUID
Hazard Class: 6.1
UN Number: 2019
Packing Group: II
IMO
Shipping Name: CHLOROANILINES, LIQUID
Hazard Class: 6.1
UN Number: 2019
Packing Group: II
RID/ADR
Shipping Name: CHLOROANILINES, LIQUID
Hazard Class: 6.1
UN Number: 2019
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T C N
Risk Phrases:
R 24/25 Toxic in contact with skin and if swallowed.
R 33 Danger of cumulative effects.
R 34 Causes burns.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 108-42-9: 2
Canada
CAS# 108-42-9 is listed on Canada's DSL List.
CAS# 108-42-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-42-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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