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1-Nitropropane
CAS No.: 108-03-2
Synonyms:
Formula: C3H7NO2
Exact Mass: 89.04770
Molecular Weight: 89.09320
PSA: 45.82000
LogP: 1.19630
Reference Price: $1,823/ton Inquiry Now
1-Nitropropane 108-03-2 MSDS
Name: 1-Nitropropane 98% Material Safety Data Sheet
Synonym: 1-Nitropane; 1-N
CAS: 108-03-2
Section 1 - Chemical Product   MSDS Name:1-Nitropropane 98% Material Safety Data Sheet
Synonym:1-Nitropane; 1-N

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
108-03-2 1-Nitropropane 98.0 203-544-9
Hazard Symbols: XN F
Risk Phrases: 10 20/21/22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if swallowed.Toxic.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. Causes digestive tract irritation.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. Vapors may cause dizziness or suffocation.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May polymerize explosively when involved in a fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame.
Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 108-03-2: United States OSHA: 25 ppm TWA; 90 mg/m3 TWA Belgium - TWA: 25 ppm VLE; 92 mg/m3 VLE France - VME: 25 ppm VME; 90 mg/m3 VME Germany: 25 ppm TWA; 92 mg/m3 TWA Germany: Skin absorber Malaysia: 25 ppm TWA; 91 mg/m3 TWA Netherlands: 25 ppm MAC; 90 mg/m3 MAC Russia: 30 mg/m3 TWA Spain: 25 ppm VLA-ED; 93 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear almost colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 7.6 mmHg @ 25 C
Viscosity: 0.844 cP 20.00
Boiling Point: 132 deg C
Freezing/Melting Point: - 108.00 - - 0.00 deg
Autoignition Temperature: 420 deg C ( 788.00 deg F)
Flash Point: 33 deg C ( 91.40 deg F)
Explosion Limits, lower: 2.20 vol %
Explosion Limits, upper: 11.00 vol %
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: .9980g/cm3
Molecular Formula: C3H7NO2
Molecular Weight: 89.09

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
May explode when heated.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 108-03-2: TZ5075000 LD50/LC50:
CAS# 108-03-2: Inhalation, rabbit: LC50 = 5000 ppm/3H; Inhalation, rat: LC50 = 3100 ppm/8H; Oral, mouse: LD50 = 800 mg/kg; Oral, rat: LD50 = 455 mg/kg.
Carcinogenicity:
1-Nitropropane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 56-70 mg/L; 5,15,30 minutes; Microtox Test; 15 degrees C; pH 7.0

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: NITROPROPANES
Hazard Class: 3
UN Number: 2608
Packing Group: III
IMO
Shipping Name: NITROPROPANES
Hazard Class: 3.3
UN Number: 2608
Packing Group: III
RID/ADR
Shipping Name: NITROPROPANES
Hazard Class: 3
UN Number: 2608
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
S 50A Do not mix with acids.
WGK (Water Danger/Protection)
CAS# 108-03-2: 2
Canada
CAS# 108-03-2 is listed on Canada's DSL List.
CAS# 108-03-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-03-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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