N,N-dimethylethanolamine 108-01-0 MSDS
Name: N N-Dimethylethanolamine 99% Material Safety Data Sheet
Synonym: Deanol; 2-Dimethylaminoethanol
CAS: 108-01-0
Section 1 - Chemical Product   MSDS Name:N N-Dimethylethanolamine 99% Material Safety Data Sheet
Synonym:Deanol; 2-Dimethylaminoethanol

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
108-01-0 N,N-Dimethylethanolamine 99 203-542-8
Hazard Symbols: C
Risk Phrases: 10 20/21/22 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if swallowed. Causes burns.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns. Lachrymator (substance which increases the flow of tears).
Skin:
May cause severe irritation and possible burns. May be harmful if absorbed through the skin.
Ingestion:
May cause burns to the digestive tract. May be harmful if swallowed.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Do NOT get water inside containers. For large fires, use water spray, fog or alcohol-resistant foam. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Do not flush into a sewer. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area. Store protected from light.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Ventilation fans and other electrical service must be non-sparking and have an explosion-proof design.
Exposure Limits CAS# 108-01-0: United Kingdom, WEL - TWA: 2 ppm TWA; 7.4 mg/m3 TWA United Kingdom, WEL - STEL: 6 ppm STEL; 22 mg/m3 STEL Netherlands: 6 ppm STEL; 22 mg/m3 STEL Netherlands: 2 ppm MAC; 7.4 mg/m3 MAC Russia: 5 mg/m3 TWA Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: Clear
Odor: Amine-like
pH: Not available.
Vapor Pressure: 6.12 mbar @ 20
Viscosity: 3.8 MPA 20.00 deg C
Boiling Point: 139 deg C @ 760 mm Hg
Freezing/Melting Point: -70 deg C
Autoignition Temperature: 235 deg C ( 455.00 deg F)
Flash Point: 40 deg C ( 104.00 deg F)
Explosion Limits, lower: 1.60 vol %
Explosion Limits, upper: 11.90 vol %
Decomposition Temperature:
Solubility in water: miscible with alcohol and ether
Specific Gravity/Density: .8870g/cm3
Molecular Formula: C4H11NO
Molecular Weight: 89.14

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources.
Incompatibilities with Other Materials:
Oxidizing agents - copper, copper alloys - zinc - acids - galvanized iron.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 108-01-0: KK6125000 LD50/LC50:
CAS# 108-01-0: Draize test, rabbit, eye: 5 uL Severe; Inhalation, mouse: LC50 = 3250 mg/m3; Inhalation, rat: LC50 = 1641 ppm/4H; Oral, rat: LD50 = 2 gm/kg; Skin, rabbit: LD50 = 1370 uL/kg.
Not available.
Carcinogenicity:
N,N-Dimethylethanolamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: 2-DIMETHYLAMINOETHANOL
Hazard Class: 8 (3)
UN Number: 2051
Packing Group: II
IMO
Shipping Name: 2-DIMETHYLAMINOETHANOL
Hazard Class: 8 (3)
UN Number: 2051
Packing Group: II
RID/ADR
Shipping Name: 2-DIMETHYLAMINOETHANOL
Hazard Class: 8
UN Number: 2051
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 108-01-0: 1
Canada
CAS# 108-01-0 is listed on Canada's DSL List.
CAS# 108-01-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-01-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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