allyl alcohol
CAS No.: 107-18-6
Synonyms:
Formula: C3H6O
Exact Mass: 58.04190
Molecular Weight: 58.07910
PSA: 20.23000
LogP: 0.16470
allyl alcohol 107-18-6 MSDS
Name: Allyl alcohol Material Safety Data Sheet
Synonym: 3-Hydroxypropene; Propenol; Propenyl alcohol
CAS: 107-18-6
Section 1 - Chemical Product   MSDS Name:Allyl alcohol Material Safety Data Sheet
Synonym:3-Hydroxypropene; Propenol; Propenyl alcohol

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
107-18-6 Allyl alcohol 99 203-470-7
Hazard Symbols: T N
Risk Phrases: 10 23/24/25 36/37/38 50

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms.
Potential Health Effects
Eye:
Causes severe eye irritation. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin irritation. May be fatal if absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
May be fatal if inhaled. May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. May cause pulmonary edema and severe respiratory disturbances. Vapors may cause dizziness or suffocation.
Chronic:
May cause liver and kidney damage. Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Approach spill from upwind. Use water spray to cool and disperse vapors, protect personnel, and dilute spills to form nonflammable mixtures. Control runoff and isolate discharged material for proper disposal.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 107-18-6: United Kingdom, WEL - TWA: 2 ppm TWA; 4.8 mg/m3 TWA United Kingdom, WEL - STEL: 4 ppm STEL; 9.7 mg/m3 STEL United States OSHA: 2 ppm TWA; 5 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 4.8 mg/m3 VLE Belgium - STEL: 4 ppm VLE; 9.6 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 4 ppm VLE; 10 mg/m3 VLE Germany: 4.8 mg/m3 TWA Germany: Skin absorber Japan: 1 ppm OEL; 2.4 mg/m3 OEL Malaysia: 0.5 ppm TWA; 1.2 mg/m3 TWA Netherlands: 2 ppm MAC; 5 mg/m3 MAC Spain: 2 ppm VLA-ED; 5 mg/m3 VLA-ED Spain: 5 ppm VLA-EC; 12 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: pungent odor - mustard-like
pH: Not available.
Vapor Pressure: 17 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 97 deg C
Freezing/Melting Point: -129 deg C
Autoignition Temperature: 378 deg C ( 712.40 deg F)
Flash Point: 21 deg C ( 69.80 deg F)
Explosion Limits, lower: 2.5%
Explosion Limits, upper: 18.0%
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 0.85
Molecular Formula: C3H6O
Molecular Weight: 58.08

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
May polymerize.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, strong acids, amines, peroxides, polymerization catalysts.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 107-18-6: BA5075000 LD50/LC50:
CAS# 107-18-6: Draize test, rabbit, eye: 20 mg Severe; Inhalation, mouse: LC50 = 500 mg/m3/2H; Inhalation, mouse: LC50 = 500 mg/m3/2H; Inhalation, rat: LC50 = 76 ppm/8H; Oral, mouse: LD50 = 96 mg/kg; Oral, mouse: LD50 = 75 mg/kg; Oral, rabbit: LD50 = 52 mg/kg; Oral, rat: LD50 = 64 mg/kg; Skin, rabbit: LD50 = 45 mg/kg.
Carcinogenicity:
Allyl alcohol - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Goldfish: LC50 = 1 mg/L; 24 Hr.; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 216-608 mg/L; 5,15,30 Minutes; Microtox test

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ALLYL ALCOHOL
Hazard Class: 6.1 (3)
UN Number: 1098
Packing Group:
IMO
Shipping Name: ALLYL ALCOHOL
Hazard Class: 6.1 (3)
UN Number: 1098
Packing Group: I
RID/ADR
Shipping Name: ALLYL ALCOHOL
Hazard Class: 6.1
UN Number: 1098
Packing group: I
USA RQ: CAS# 107-18-6: 100 lb final RQ; 45.4 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 10 Flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 107-18-6: 2
Canada
CAS# 107-18-6 is listed on Canada's DSL List.
CAS# 107-18-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107-18-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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