ethylenediamine 107-15-3 MSDS
Name: Ethylenediamine Material Safety Data Sheet
Synonym: 1,2-Diaminoethane; 1,2-Ethanediamine; Dimethylenediamine; EDA
CAS: 107-15-3
Section 1 - Chemical Product   MSDS Name:Ethylenediamine Material Safety Data Sheet
Synonym:1,2-Diaminoethane; 1,2-Ethanediamine; Dimethylenediamine; EDA

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
107-15-3 Ethylenediamine >98 203-468-6
Hazard Symbols: C
Risk Phrases: 10 21/22 34 42/43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin and if swallowed. Causes burns. May cause sensitization by inhalation and skin contact.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns. Low vapor concentrations may cause a temporary visual disturbance known as 'blue haze' or 'halo vision'.
Lachrymator (substance which increases the flow of tears).
Skin:
Harmful if absorbed through the skin. Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal tract burns. May cause liver and kidney damage. May be harmful if swallowed.
Inhalation:
May cause severe allergic respiratory reaction. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause liver and kidney damage. Causes chemical burns to the respiratory tract. May cause asthma.
Chronic:
May cause liver and kidney damage. Repeated exposure may cause allergic respiratory reaction (asthma).

Section 4 - FIRST AID MEASURES
  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Solid streams of water may be ineffective and spread material. Use water spray, dry chemical, "alcohol resistant" foam, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation. Evacuate unnecessary personnel. Approach spill from upwind. Use water spray to cool and disperse vapors, protect personnel, and dilute spills to form nonflammable mixtures.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapor or mist. Use only with adequate ventilation or respiratory protection.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Store protected from moisture. Do not store in copper or copper alloy storage vessels.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 107-15-3: United States OSHA: 10 ppm TWA; 25 mg/m3 TWA Belgium - TWA: 10 ppm VLE; 25 mg/m3 VLE France - VME: 10 ppm VME; 25 mg/m3 VME France - VLE: 15 ppm VLE; 35 mg/m3 VLE Germany: 10 ppm TWA; 25 mg/m3 TWA Germany: Skin absorber Japan: 10 ppm OEL; 25 mg/m3 OEL Malaysia: 10 ppm TWA; 25 mg/m3 TWA Netherlands: 7 ppm MAC; 18 mg/m3 MAC Russia: 2 mg/m3 TWA Spain: 10 ppm VLA-ED; 25 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Viscous liquid
Color: clear, colorless
Odor: ammonia-like
pH: 11.9 (25% aq soln)
Vapor Pressure: 12 mm Hg @ 25 deg C
Viscosity: 1.54 mPas 25 deg C
Boiling Point: 118 deg C @ 760 mm Hg
Freezing/Melting Point: 8.5 deg C
Autoignition Temperature: 385 deg C ( 725.00 deg F)
Flash Point: 34 deg C ( 93.20 deg F)
Explosion Limits, lower: 2.6 vol %
Explosion Limits, upper: 14.2 vol %
Decomposition Temperature: >120 deg C
Solubility in water: Soluble.
Specific Gravity/Density: .8980 g/ml
Molecular Formula: C2H8N2
Molecular Weight: 60.10

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Absorbs carbon dioxide from air to form nonvolatile carbonate.
Conditions to Avoid:
Ignition sources, moisture, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, copper, copper alloys.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, ammonia and/or derivatives.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 107-15-3: KH8575000 LD50/LC50:
CAS# 107-15-3: Draize test, rabbit, eye: 750 ug Severe; Draize test, rabbit, eye: 750 ug/24H Severe; Inhalation, mouse: LC50 = 300 mg/m3; Oral, mouse: LD50 = 1 gm/kg; Oral, rat: LD50 = 1200 mg/kg; Skin, rabbit: LD50 = 730 uL/kg.
Skin, rabbit, LD50: 730 uL/kg = 649.7 mg/kg.
4000 ppm for 8 hours killed 6/6 rats, while 2000 ppm produced no lethality (Doc of TLV).
Carcinogenicity:
Ethylenediamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Fathead Minnow: LC50 = 115.7 mg/L; 96 Hr.; Static ConditionFish: Rainbow trout: LC50 = 230.0 mg/L; 96 Hr.; Static ConditionWater flea EC50 = 0.88 mg/L; 48 Hr.; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 20.0 mg/L; 15 Minutes; Microtox testChub (fresh water) 60ppm/24H (lethal) Rainbow trout LC50=230 mg/L/48H

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ETHYLENEDIAMINE
Hazard Class: 8 (3)
UN Number: 1604
Packing Group: II
IMO
Shipping Name: ETHYLENEDIAMINE
Hazard Class: 8 (3)
UN Number: 1604
Packing Group: II
RID/ADR
Shipping Name: ETHYLENEDIAMINE
Hazard Class: 8
UN Number: 1604
Packing group: II
USA RQ: CAS# 107-15-3: 5000 lb final RQ; 2270 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 107-15-3: 2
Canada
CAS# 107-15-3 is listed on Canada's DSL List.
CAS# 107-15-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107-15-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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