Allylamine
CAS No.: 107-11-9
Synonyms:
Formula: C3H7N
Exact Mass: 57.05780
Molecular Weight: 57.09440
PSA: 26.02000
LogP: 0.83140
Allylamine 107-11-9 MSDS
Name: Allylamine 97% Material Safety Data Sheet
Synonym: 3-Amino-1-propene;3-aminopropylene;2-propen-1-amin
CAS: 107-11-9
Section 1 - Chemical Product   MSDS Name:Allylamine 97% Material Safety Data Sheet
Synonym:3-Amino-1-propene;3-aminopropylene;2-propen-1-amin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
107-11-9 Allylamine 97.0 203-463-9
Hazard Symbols: T F
Risk Phrases: 11 23/24/25

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Toxic by inhalation, in contact with skin and if swallowed.Corrosive.
Potential Health Effects
Eye:
Causes severe eye burns. Vapor or mist may cause irritation and severe burns. May cause conjunctivitis. Lachrymator (substance which increases the flow of tears).
Skin:
May be fatal if absorbed through the skin. Causes severe burns.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
May be fatal if inhaled. Exposure to high concentrations may produce narcosis, nausea and loss of consciousness. Causes respiratory tract irritation with possible burns. May cause severe tearing, conjunctivitis, corneal edema, coughing, nausea, and pulmonary edema.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Combustion generates toxic fumes. Use water spray to keep fire-exposed containers cool. Extremely flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Will be easily ignited by heat, sparks or flame. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Use only in a chemical fume hood.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from acids.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use only under a chemical fume hood.
Exposure Limits CAS# 107-11-9: Germany: 5 mg/m3 TWA Germany: Skin absorber Russia: 0.5 mg/m3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear light yellow
Odor: Strong ammoniacal odor
pH: Not available.
Vapor Pressure: 242 mm Hg @25C
Viscosity: 0.44 cP 25 deg C
Boiling Point: 55-58C
Freezing/Melting Point: -123 deg C
Autoignition Temperature: 705 deg F ( 373.89 deg C)
Flash Point: -20 deg C ( -4.00 deg F)
Explosion Limits, lower: 2.0 vol %
Explosion Limits, upper: 22.00 vol %
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: .7610g/cm3
Molecular Formula: C3H7N
Molecular Weight: 57.09

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Metals, oxidizing agents, acids, amines, halogenated agents, alkalies, chlorine, hypochlorite.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 107-11-9: BA5425000 LD50/LC50:
CAS# 107-11-9: Draize test, rabbit, skin: 500 mg/24H Severe; Inhalation, rat: LC50 = 177 ppm/8H; Oral, mouse: LD50 = 57 mg/kg; Oral, rat: LD50 = 102 mg/kg; Skin, rabbit: LD50 = 35 mg/kg.
Carcinogenicity:
Allylamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 16 mg/L; 5, 15 minutes; Microtox test; 14.9-15.1 degrees C

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ALLYLAMINE
Hazard Class: 6.1 (3)
UN Number: 2334
Packing Group:
IMO
Shipping Name: ALLYLAMINE
Hazard Class: 6.1 (3)
UN Number: 2334
Packing Group: I
RID/ADR
Shipping Name: ALLYLAMINE
Hazard Class: 6.1
UN Number: 2334
Packing group: I

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 107-11-9: 2
Canada
CAS# 107-11-9 is listed on Canada's DSL List.
CAS# 107-11-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107-11-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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