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Allyl chloride 107-05-1 MSDS
Name: Allyl Chloride 98% Material Safety Data Sheet
Synonym: 3-Chloropropene; 3-Chloroprene
CAS: 107-05-1
Section 1 - Chemical Product   MSDS Name:Allyl Chloride 98% Material Safety Data Sheet
Synonym:3-Chloropropene; 3-Chloroprene

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
107-05-1 Allyl chloride 98 % 203-457-6
Hazard Symbols: T F N
Risk Phrases: 11 26 50

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Very toxic by inhalation. Very toxic to aquatic organisms.Highly flammable.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause lung damage. Vapors may cause dizziness or suffocation.
Chronic:
May cause liver and kidney damage. May cause cancer according to animal studies. May cause lung damage.

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of water. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May polymerize explosively when involved in a fire. Vapors may form an explosive mixture with air. Containers may explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: Pungent odor.
pH: Not available.
Vapor Pressure: 367 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 45 deg C
Freezing/Melting Point: -135 deg C
Autoignition Temperature: 485 deg C ( 905.00 deg F)
Flash Point: -31.6 deg C ( -24.88 deg F)
Explosion Limits, lower: 2.9
Explosion Limits, upper: 11.2
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 0.94
Molecular Formula: C3H5Cl
Molecular Weight: 76.488

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Explosion hazard when exposed to acids or oxidizing agents, Explosive reaction with alkyl aluminum chlorides + aromatic hydrocarbons (e.g., benzene or toluene). Violently exothermic polymerization reaction with Lewis acids (e.g., aluminum chloride, boron trifluoride and sulfuric acid). Incompatible with ethylene imine, ethylenediamine, chlorosulfonic acid, oleum, sodium hydroxide and nitric acid.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 107-05-1: UC7350000 LD50/LC50:
CAS# 107-05-1: Draize test, rabbit, eye: 500 mg Moderate; Inhalation, mouse: LC50 = 11500 mg/m3/2H; Inhalation, mouse: LC50 = 6600 mg/m3; Inhalation, rat: LC50 = 11 gm/m3/2H; Inhalation, rat: LC50 = 8200 mg/m3; Oral, mouse: LD50 = 425 mg/kg; Oral, mouse: LD50 = 500 mg/kg; Oral, rabbit: LD50 = 300 mg/kg; Oral, rat: LD50 = 460 mg/kg; Oral, rat: LD50 = 450 mg/kg; Skin, rabbit: LD50 = 2066 mg/kg.
Carcinogenicity:
Allyl chloride - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ALLYL CHLORIDE
Hazard Class: 3
UN Number: 1100
Packing Group: I
IMO
Shipping Name: ALLYL CHLORIDE
Hazard Class: 3.1
UN Number: 1100
Packing Group: I
RID/ADR
Shipping Name: ALLYL CHLORIDE
Hazard Class: 3
UN Number: 1100
Packing group: I
USA RQ:CAS# 107-05-1: 1000 lb final RQ; 454 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F N
Risk Phrases:
R 11 Highly flammable.
R 26 Very toxic by inhalation.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 107-05-1: 2
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 107-05-1 is listed on Canada's DSL List.
CAS# 107-05-1 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 107-05-1: OEL-ARAB Republic of Egypt:TWA 1 ppm (3 mg/m3)
OEL-AUSTRALIA:TWA 1 ppm (3 mg/m3);STEL 2 ppm (6 mg/m3)
OEL-AUSTRIA:TWA 1 ppm (3 mg/m3)
OEL-BELGIUM:TWA 1 ppm (3 mg/m3);STEL 2 ppm (5 mg/m3)
OEL-BELGIUM:TWA 1 ppm (3 mg/m3);STEL 2 ppm (6 mg/m3)
OEL-CZECHOSLOVAKIA:TWA 1 mg/m3;STEL 2 mg/m3
OEL-DENMARK:TWA 1 ppm (3 mg/m3)
OEL-FINLAND:TWA 1 ppm (3 mg/m3);STEL 3 ppm (9 mg/m3)
OEL-FRANCE:TWA 1 ppm (3 mg/m3)
OEL-GERMANY:TWA 1 ppm (3 mg/m3)
OEL-GERMANY:TWA 1 ppm (3 mg/m3);Carcinogen
OEL-HUNGARY:TWA 3 mg/m3;STEL 6 mg/m3
OEL-INDIA:TWA 1 ppm (3 mg/m3);STEL 2 ppm (6 mg/m3
OEL-THE NETHERLANDS:TWA 1 ppm (3 mg/m3)
OEL-RUSSIA:STEL 0.3 mg/m3
OEL-RUSSIA:STEL 0.3 mg/m3;Skin
OEL-SWITZERLAND:TWA 1 ppm (3 mg/m3);STEL 2 ppm (6 mg/m3)
OEL-TURKEY:TWA 1 ppm (3 mg/m3)
OEL-UNITED KINGDOM:TWA 1 ppm (3 mg/m3);STEL 2 ppm (6 mg/m3)
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 107-05-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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