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Allyl bromide 106-95-6 MSDS
Name: Allyl Bromide Stabilized with Ca. 300 ppm Propylene Oxide 99% Material Safety Data Sheet
Synonym: 3-Bromopropene; 3-Bromopropylene
CAS: 106-95-6
Section 1 - Chemical Product   MSDS Name:Allyl Bromide Stabilized with Ca. 300 ppm Propylene Oxide 99% Material Safety Data Sheet
Synonym:3-Bromopropene; 3-Bromopropylene

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
106-95-6 Allyl Bromide 98 203-446-6
Hazard Symbols: T F
Risk Phrases: 11 25

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Toxic if swallowed.Lachrymator (substance which increases the flow of tears).Highly flammable.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
May cause severe skin irritation with possible burns, especially if skin is wet or moist.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. May cause perforation of the digestive tract.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
May cause liver and kidney damage.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Material will burn in a fire. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas. May be ignited by friction, heat, sparks, or flame. May polymerize explosively when involved in a fire. Containers may explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Exposure Limits CAS# 106-95-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: Pungent odor.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 71 deg C
Freezing/Melting Point: -115 deg C
Autoignition Temperature: 295 deg C ( 563.00 deg F)
Flash Point: -1.1 deg C ( 30.02 deg F)
Explosion Limits, lower: 4.4
Explosion Limits, upper: 7.3
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 1.42 @ 20 C
Molecular Formula: C3H5Br
Molecular Weight: 120.939

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures. Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents and strong bases. Contact with aluminum chloride, boron trifluoride and sulfuric acid may cause exothermic polymerization. Reacts violently with oxidants (e.g., bromine difluoride, chromium (VI) oxide, potassium permanganate or sodium peroxide.) Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 106-95-6: UC7090000 LD50/LC50:
CAS# 106-95-6: Inhalation, mouse: LC50 = 4110 mg/m3/2H; Inhalation, rat: LC50 = 10 gm/m3/30M; Inhalation, rat: LC50 = 10000 mg/m3/2H; Oral, rat: LD50 = 120 mg/kg.
Carcinogenicity:
Allyl Bromide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ALLYL BROMIDE
Hazard Class: 3 (6.1)
UN Number: 1099
Packing Group: I
IMO
Shipping Name: ALLYL BROMIDE
Hazard Class: 3.2 (6.1)
UN Number: 1099
Packing Group: I
RID/ADR
Shipping Name: ALLYL BROMIDE
Hazard Class: 3
UN Number: 1099
Packing group: I

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 25 Toxic if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 106-95-6: No information available.
Canada
CAS# 106-95-6 is listed on Canada's DSL List.
CAS# 106-95-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-95-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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