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Glycidyl methacrylate 106-91-2 MSDS
Name: Glycidyl methacrylate 97% (stabilized with 90-110 ppm MEHQ) Material Safety Data Sheet
Synonym: 2,3-Epoxypropyl methacrylate; 2,3-Epoxy-1-propanol methacrylate; 2,3-Epoxypropyl ester methacrylic acid; Glycidyl-alpha-methyl acrylate
CAS: 106-91-2
Section 1 - Chemical Product   MSDS Name:Glycidyl methacrylate 97% (stabilized with 90-110 ppm MEHQ) Material Safety Data Sheet
Synonym:2,3-Epoxypropyl methacrylate; 2,3-Epoxy-1-propanol methacrylate; 2,3-Epoxypropyl ester methacrylic acid; Glycidyl-alpha-methyl acrylate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
106-91-2 Glycidyl methacrylate 97 203-441-9
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/38 43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin. May cause sensitization by skin contact.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation and burns.
Skin:
Causes skin irritation. Harmful if absorbed through the skin. Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Laboratory experiments have resulted in mutagenic effects.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Do NOT get water inside containers.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not ingest or inhale. Store protected from light. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Store protected from light.
Store in mild steel, stainless steel, or aluminum.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 106-91-2: Netherlands: 0.05 ppm MAC; 0.24 mg/m3 MAC CAS# 150-76-5: Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Germany: 5 mg/m3 TWA Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear polyethylene gloves, apron, and/or clothing.
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 13.3 mbar @ 20
Viscosity: 2.5 mPas 20 deg C
Boiling Point: 189 deg C @ 760mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: 389 deg C ( 732.20 deg F)
Flash Point: 76 deg C ( 168.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible in almost all common organic so
Specific Gravity/Density: 1.0700g/cm3
Molecular Formula: C7H10O3
Molecular Weight: 142.15

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable only if stored and handled under recommended conditions. The stability of the product depends upon the availability of both dissolved oxygen and MEHQ inhibitor(CAS=150-76-5). The presence of oxygen is necessary for the MEHQ to function effectively. The product should never be stored under an inert gas atmosphere, but should always be stored under an atmosphere containing 5-21% oxygen by volume.
Conditions to Avoid:
Incompatible materials, light, ignition sources, excess heat, loss of inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, peroxides.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 106-91-2: OZ4375000 CAS# 150-76-5: SL7700000 LD50/LC50:
CAS# 106-91-2: Draize test, rabbit, eye: 100 uL Moderate; Draize test, rabbit, skin: 500 uL/24H Severe; Inhalation, rat: LC50 = 45 ppm/4H; Oral, mouse: LD50 = 390 mg/kg; Oral, rat: LD50 = 500 mg/kg; Skin, rabbit: LD50 = 450 uL/kg.
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
Carcinogenicity:
Glycidyl methacrylate - Not listed by ACGIH, IARC, or NTP.
4-Methoxyphenol - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 106-91-2: 2
CAS# 150-76-5: 1
Canada
CAS# 106-91-2 is listed on Canada's DSL List.
CAS# 150-76-5 is listed on Canada's DSL List.
CAS# 106-91-2 is not listed on Canada's Ingredient Disclosure List.
CAS# 150-76-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-91-2 is listed on the TSCA inventory.
CAS# 150-76-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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