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heptan-3-one
CAS No.: 106-35-4
Synonyms:
Formula: C7H14O
Exact Mass: 114.10400
Molecular Weight: 114.18500
PSA: 17.07000
LogP: 2.15570
Reference Price: $99/L Inquiry Now
heptan-3-one 106-35-4 MSDS
Name: 3-Heptanone 98% Material Safety Data Sheet
Synonym: Butyl Ethyl Ketone; Heptan-3-One
CAS: 106-35-4
Section 1 - Chemical Product   MSDS Name:3-Heptanone 98% Material Safety Data Sheet
Synonym:Butyl Ethyl Ketone; Heptan-3-One

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
106-35-4 3-Heptanone 98 203-388-1
Hazard Symbols: XN
Risk Phrases: 10 36 20

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Irritating to eyes. Harmful by inhalation.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness or suffocation. Harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Water may be ineffective. Do NOT use straight streams of water.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 106-35-4: United Kingdom, WEL - TWA: 35 ppm TWA; 166 mg/m3 TWA United Kingdom, WEL - STEL: 100 ppm STEL; 475 mg/m3 STEL United States OSHA: 50 ppm TWA; 230 mg/m3 TWA Belgium - TWA: 50 ppm VLE; 95 mg/m3 VLE France - VME: 50 ppm VME; 230 mg/m3 VME Germany: 10 ppm TWA; 47 mg/m3 TWA Malaysia: 50 ppm TWA; 234 mg/m3 TWA Netherlands: 35 ppm MAC; 163 mg/m3 MAC Spain: 20 ppm VLA-ED; 95 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Clear liquid
Color: slightly yellow
Odor: fatty odor
pH: Not available.
Vapor Pressure: 5.5 hPa @ 20 C
Viscosity: Not available.
Boiling Point: 146- 149 deg C @ 760.00mmHg
Freezing/Melting Point: -39 deg C
Autoignition Temperature: 390 deg C ( 734.00 deg F)
Flash Point: 41 deg C ( 105.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .8180g/cm3
Molecular Formula: C7H14O
Molecular Weight: 114.19

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 106-35-4: MJ5250000 LD50/LC50:
CAS# 106-35-4: Draize test, rabbit, eye: 100 mg Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H Moderate; Oral, rat: LD50 = 2760 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
Carcinogenicity:
3-Heptanone - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: KETONES, LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1224
Packing Group: III
IMO
Shipping Name: KETONES, LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1224
Packing Group: III
RID/ADR
Shipping Name: KETONES, LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1224
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20 Harmful by inhalation.
R 36 Irritating to eyes.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24 Avoid contact with skin.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 106-35-4: 1
Canada
CAS# 106-35-4 is listed on Canada's DSL List.
CAS# 106-35-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-35-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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