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DL-sec-Butyl acetate
CAS No.: 105-46-4
Synonyms:
Formula: C6H12O2
Exact Mass: 116.08400
Molecular Weight: 116.15800
PSA: 26.30000
LogP: 1.34800
Reference Price: $727/ton Inquiry Now
DL-sec-Butyl acetate 105-46-4 MSDS
Name: Dl-sec-Butyl Acetate 99% Material Safety Data Sheet
Synonym: Acetic acid, sec-butyl ester; Acetic acid, 2-butoxy ester; Acetic acid 1-methylpropyl ester (9CI); 2-butanol acetate; sec-butyl acetate; 2-butyl acetate; sec-butyl alcohol acetat
CAS: 105-46-4
Section 1 - Chemical Product   MSDS Name:Dl-sec-Butyl Acetate 99% Material Safety Data Sheet
Synonym:Acetic acid, sec-butyl ester; Acetic acid, 2-butoxy ester; Acetic acid 1-methylpropyl ester (9CI); 2-butanol acetate; sec-butyl acetate; 2-butyl acetate; sec-butyl alcohol acetat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
105-46-4 DL-SEC-BUTYL ACETATE 99% 203-300-1
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Vapors cause eye irritation.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. Exposure produces central nervous system depression. Vapor or mist is irritating to the mucous membranes and upper respiratory tract.
Chronic:
Chronic inhalation may cause effects similar to those of acute inhalation.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Water may be ineffective.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wash area with soap and water.
Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Use only in a chemical fume hood. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use only under a chemical fume hood.
Exposure Limits CAS# 105-46-4: United Kingdom, WEL - TWA: 200 ppm TWA; 966 mg/m3 TWA United Kingdom, WEL - STEL: 250 ppm STEL; 1210 mg/m3 STEL United States OSHA: 200 ppm TWA; 950 mg/m3 TWA Belgium - TWA: 200 ppm VLE; 964 mg/m3 VLE France - VME: 200 ppm VME; 950 mg/m3 VME Germany: 100 ppm TWA; 480 mg/m3 TWA Malaysia: 200 ppm TWA; 950 mg/m3 TWA Netherlands: 200 ppm MAC; 950 mg/m3 MAC Spain: 200 ppm VLA-ED; 966 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: Fruity odor
pH: Not available.
Vapor Pressure: 25 mm Hg @ 25C
Viscosity: Not available.
Boiling Point: 112 deg C @ 760.00mm Hg
Freezing/Melting Point: -73.5 deg C
Autoignition Temperature: 390 deg C ( 734.00 deg F)
Flash Point: 16 deg C ( 60.80 deg F)
Explosion Limits, lower: 1.70 vol %
Explosion Limits, upper: 9.80 vol %
Decomposition Temperature:
Solubility in water: 0.8g/100g H2O @ 20C
Specific Gravity/Density: 0.862-0.866 @ 20C
Molecular Formula: C6H12O2
Molecular Weight: 116.16

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, strong bases, amines, nitrates.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 105-46-4: AF7380000 LD50/LC50:
CAS# 105-46-4: Oral, rat: LD50 = 3200 mg/kg.
Carcinogenicity:
DL-SEC-BUTYL ACETATE - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: BUTYL ACETATES
Hazard Class: 3
UN Number: 1123
Packing Group: II
IMO
Shipping Name: BUTYL ACETATES
Hazard Class: 3.2
UN Number: 1123
Packing Group: II
RID/ADR
Shipping Name: BUTYL ACETATES
Hazard Class: 3
UN Number: 1123
Packing group: II
USA RQ: CAS# 105-46-4: 5000 lb final RQ (Listed under Butyl acetate); 2270 kg fi

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 105-46-4: No information available.
Canada
CAS# 105-46-4 is listed on Canada's DSL List.
CAS# 105-46-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 105-46-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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