3-Diethylaminopropylamine 104-78-9 MSDS
Name: 3-Diethylaminopropylamine 99+% Material Safety Data Sheet
Synonym: N,N-Diethyl-1,3-Propanediamin
CAS: 104-78-9
Section 1 - Chemical Product   MSDS Name:3-Diethylaminopropylamine 99+% Material Safety Data Sheet
Synonym:N,N-Diethyl-1,3-Propanediamin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
104-78-9 3-Diethylaminopropylamine 99 203-236-4
Hazard Symbols: C
Risk Phrases: 10 21/22 34 43

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin and if swallowed. Causes burns. May cause sensitization by skin contact.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
Harmful if absorbed through the skin. May cause severe irritation and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. May be harmful if swallowed.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Flammable liquid and vapor. Vapors from liquefied gas are initially heavier than air and spread along ground.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not ingest or inhale.
Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area. Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 104-78-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 2.5 hPa @ 20.0
Viscosity: 1.3 mPas 20 deg C
Boiling Point: 159 deg C @ 760.00mm Hg
Freezing/Melting Point: -60 deg C
Autoignition Temperature: 260 deg C ( 500.00 deg F)
Flash Point: 53 deg C ( 127.40 deg F)
Explosion Limits, lower: 1.40 vol %
Explosion Limits, upper: 11.60 vol %
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: .8260g/cm3
Molecular Formula: C7H18N2
Molecular Weight: 130.23

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Acid chlorides, carbon dioxide, acid anhydrides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 104-78-9: TX7350000 LD50/LC50:
CAS# 104-78-9: Oral, mouse: LD50 = 425 mg/kg; Oral, rat: LD50 = 550 mg/kg; Skin, rabbit: LD50 = 750 uL/kg.
Carcinogenicity:
3-Diethylaminopropylamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: DIETHYLAMINOPROPYLAMINE
Hazard Class: 3 (8)
UN Number: 2684
Packing Group: III
IMO
Shipping Name: 3-(DIETHYLAMINO)PROPYLAMINE
Hazard Class: 3.3 (8)
UN Number: 2684
Packing Group: III
RID/ADR
Shipping Name: DIETHYLAMINOPROPYLAMINE
Hazard Class: 3
UN Number: 2684
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 104-78-9: 1
Canada
CAS# 104-78-9 is listed on Canada's DSL List.
CAS# 104-78-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 104-78-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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