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2-Ethylhexylamine 104-75-6 MSDS
Name: 2-Ethylhexylamine 99% Material Safety Data Sheet
Synonym:
CAS: 104-75-6
Section 1 - Chemical Product   MSDS Name:2-Ethylhexylamine 99% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
104-75-6 2-Ethylhexylamine 99 203-233-8
Hazard Symbols: C
Risk Phrases: 10 20/21/22 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if swallowed. Causes burns.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
Harmful if absorbed through the skin. Causes severe skin irritation and possible burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause burns to the gastrointestinal tract.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Vapors may cause dizziness or suffocation.
Chronic:
May cause liver and kidney damage. Prolonged exposure may cause systemic effects.

Section 4 - FIRST AID MEASURES
  Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use dry chemical, carbon dioxide, or alcohol-resistant foam. Contact professional fire-fighters immediately.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation. Cover with a 90:10 mixture of sand/soda ash. Place in a container. Flush area with water.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 104-75-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear
Odor: musky, ammonia odor
pH: Not available.
Vapor Pressure: 1.6 hPa @ 20 C
Viscosity: 1.1 MPA 20.00 deg C
Boiling Point: 169 deg C @ 760.00mm Hg
Freezing/Melting Point: -76 deg C
Autoignition Temperature: 295 deg C ( 563.00 deg F)
Flash Point: 50 deg C ( 122.00 deg F)
Explosion Limits, lower: .80 vol %
Explosion Limits, upper: 6.00 vol %
Decomposition Temperature:
Solubility in water: 2.5 g/l (20 c)
Specific Gravity/Density: .7890g/cm3
Molecular Formula: C8H19N
Molecular Weight: 129.25

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, metals, excess heat, electrical sparks, exposure to flame.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, alcohols, aluminum, copper, vinyl acetate, zinc, tin, aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), isocyanates (e.g. methyl isocyanate), ketones (e.g. acetone, acetophenone, MEK, MIBK), lead, organic anhydrides.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 104-75-6: MQ5250000 LD50/LC50:
CAS# 104-75-6: Draize test, rabbit, eye: 50 ug/24H Severe; Draize test, rabbit, skin: 750 ug/24H Severe; Oral, rat: LD50 = 450 mg/kg; Skin, rabbit: LD50 = 600 uL/kg.
Carcinogenicity:
2-Ethylhexylamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: 2-ETHYLHEXYLAMINE
Hazard Class: 3 (8)
UN Number: 2276
Packing Group: III
IMO
Shipping Name: 2-ETHYLHEXYLAMINE
Hazard Class: 3.3 (8)
UN Number: 2276
Packing Group: III
RID/ADR
Shipping Name: 2-ETHYLHEXYLAMINE
Hazard Class: 3
UN Number: 2276
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
WGK (Water Danger/Protection)
CAS# 104-75-6: 2
Canada
CAS# 104-75-6 is listed on Canada's DSL List.
CAS# 104-75-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 104-75-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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