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Triethanolamine
CAS No.: 102-71-6
Synonyms:
Formula: C6H15NO3
Exact Mass: 149.10500
Molecular Weight: 149.18800
PSA: 63.93000
LogP: -1.73470
Reference Price: $19/kg Inquiry Now
Triethanolamine 102-71-6 MSDS
Name: 2-Chloroethyl vinyl ether ca. 95% (stabilized with MEHQ and Material Safety Data Sheet
Synonym: (2-Chloroethoxy)ethene; 2-Vinyloxyethyl chloride; Vinyl 2-chloroethyl ether
CAS: 102-71-6
Section 1 - Chemical Product   MSDS Name:2-Chloroethyl vinyl ether ca. 95% (stabilized with MEHQ and Material Safety Data Sheet
Synonym:(2-Chloroethoxy)ethene; 2-Vinyloxyethyl chloride; Vinyl 2-chloroethyl ether

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
102-71-6 2-Chloroethyl vinyl ether 95 203-799-6
Hazard Symbols: XN F
Risk Phrases: 11 22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Harmful if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or suffocation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. May form explosive peroxides. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. After opening, purge container with nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Addition of water or appropriate reducing materials will lessen peroxide formation.
Containers should be dated when opened and tested periodically for the presence of peroxides. Should crystals form in a peroxidizable liquid, peroxidation may have occurred and the product should be considered extremely dangerous. In this instance, the container should only be opened remotely by professionals. All peroxidizable substances should be stored away from heat and light and be protected from ignition sources.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 102-71-6: Belgium - TWA: 5 mg/m3 VLE Germany: 5 mg/m3 TWA (inhalable fraction) Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED CAS# 110-75-8: CAS# 150-76-5: Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Germany: 5 mg/m3 TWA Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 27 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 109 deg C @ 760 mm Hg
Freezing/Melting Point: -70 deg C
Autoignition Temperature: Not available.
Flash Point: 16 deg C ( 60.80 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.04 g/cm3
Molecular Formula: C4H7ClO
Molecular Weight: 106.55

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Under normal storage conditions, peroxidizable compounds can form and accumulate peroxides which may explode when subjected to heat or shock. This material is most hazardous when peroxide levels are concentrated by distillation or evaporation.
Conditions to Avoid:
Light, ignition sources, excess heat, mechanical shock.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, phosgene gas.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 102-71-6: KL9275000 CAS# 110-75-8: KN6300000 CAS# 150-76-5: SL7700000 LD50/LC50:
CAS# 102-71-6: Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 10 mg Mild; Draize test, rabbit, skin: 560 mg/24H Mild; Oral, mouse: LD50 = 5846 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg; Oral, rat: LD50 = 4920 uL/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rat: LD50 = >16 mL/kg.
CAS# 110-75-8: Oral, rat: LD50 = 210 mg/kg; Skin, rabbit: LD50 = 2400 mg/kg.
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
Carcinogenicity:
Triethanolamine - Not listed by ACGIH, IARC, or NTP.
2-Chloroethyl vinyl ether - Not listed by ACGIH, IARC, or NTP.
MEHQ - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish toxicity: LC50 (24-96 hr) bluegill sunfish 452-350 mg/l Invertebrate toxicity: LC50 (48 hr) contact Eisenia foetida 33 g/cm2 LC50 (14 days) absorbed in soil Eisenia foetida 740 mg/kg

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.*
Hazard Class: 3 (6.1)
UN Number: 1992
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3.2 (6.1)
UN Number: 1992
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1992
Packing group: II
USA RQ: CAS# 110-75-8: 1000 lb final RQ; 454 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 102-71-6: 1
CAS# 110-75-8: No information available.
CAS# 150-76-5: 1
Canada
CAS# 102-71-6 is listed on Canada's DSL List.
CAS# 110-75-8 is listed on Canada's NDSL List.
CAS# 150-76-5 is listed on Canada's DSL List.
CAS# 102-71-6 is listed on Canada's Ingredient Disclosure List.
CAS# 110-75-8 is listed on Canada's Ingredient Disclosure List.
CAS# 150-76-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-71-6 is listed on the TSCA inventory.
CAS# 110-75-8 is listed on the TSCA inventory.
CAS# 150-76-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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