Triallylamine 102-70-5 MSDS
Name: Triallylamine 98% Material Safety Data Sheet
Synonym: N,N-Di-2-propenyl-2-propen-1-amin
CAS: 102-70-5
Section 1 - Chemical Product   MSDS Name:Triallylamine 98% Material Safety Data Sheet
Synonym:N,N-Di-2-propenyl-2-propen-1-amin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
102-70-5 Triallylamine 98 203-048-2
Hazard Symbols: T F
Risk Phrases: 10 22 24 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Toxic in contact with skin. Causes burns.
Potential Health Effects
The toxicological properties of this material have not been investigated. Use appropriate procedures to prevent opportunities for direct contact with the skin or eyes and to prevent inhalation.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 102-70-5: Russia: 1 mg/m3 TWA Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: light yellow
Odor: ammonia-like
pH: Not available.
Vapor Pressure: 90 mmHg @ 80 C
Viscosity: Not available.
Boiling Point: 150.0 - 151.0 deg C
Freezing/Melting Point: 0 deg C
Autoignition Temperature: 204 deg C ( 399.20 deg F)
Flash Point: 39 deg C ( 102.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 2G/L (20C) IN WATER
Specific Gravity/Density: .7900g/cm3
Molecular Formula: (CH2=CHCH2)3N
Molecular Weight: 137.22

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 102-70-5: XX5950000 LD50/LC50:
CAS# 102-70-5: Inhalation, rat: LC50 = 554 ppm/8H; Oral, mouse: LD50 = 492 mg/kg; Oral, rat: LD50 = 1030 mg/kg; Skin, rabbit: LD50 = 400 uL/kg.
Carcinogenicity:
Triallylamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Discarded triallylamine is a hazardous waste. Do not discharge to surface water or to a sewer system.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: TRIALLYLAMINE
Hazard Class: 3 (8)
UN Number: 2610
Packing Group: III
IMO
Shipping Name: TRIALLYLAMINE
Hazard Class: 3 (8)
UN Number: 2610
Packing Group: III
RID/ADR
Shipping Name: TRIALLYLAMINE
Hazard Class: 3
UN Number: 2610
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 24 Toxic in contact with skin.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 102-70-5: No information available.
Canada
CAS# 102-70-5 is listed on Canada's NDSL List.
CAS# 102-70-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-70-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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