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manganese(2+),1,2,3,5-tetramethylcyclopenta-1,3-diene 101932-75-6 MSDS

Section 1: Product Identification
   Chemical Name:       Bis(tetramethylcyclopentadienyl)manganese, min. 98%    
   CAS Registry Number:       101932-75-6    
   Formula:       [(CH3)4C5H]2Mn    
   EINECS Number:       none    
   Chemical Family:       metallocene    
   Synonym:       1,1', 2,2',3,3',4,4'-Octamethylmanganocene    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       101932-75-6       100%       0.2mg/m3 (as Mn)       5mg/m3 (as Mn-    

Section 3: Hazards Identification
   May be irritating to eyes, skin and respiratory tract. May be harmful if swallowed. Some manganese
   Emergency Overview:
   compounds are known to affect the central nervous system. Possible risk of irreversible effects.
   Primary Routes of Exposure:       Inhalation and Ingestion    
   Eye Contact:       May cause slight to mild irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Dust may be irritating to the nose, mucous membranes and respiratory tract, and cause chronic health
   Inhalation:
   problems.
   Ingestion:       No information available on the physiological effects of ingestion.    
   Acute Health Affects:       May be irritating to skin, eyes and respiratory tract.    
   Prolonged exposure to manganese containing dust may produce manganese pneumonitis and manganese
   Chronic Health Affects:       poisoning. Symptoms include sleepiness, weakness and emotional disturbances. Equivocal studies have    
   shown manganese may decrease fertility in men. Possible risk of irreversible effects.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic manganese oxide fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Flammable solid. Dust may form explosive mixtures with air.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry area away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       red xtl.    
   Molecular Weight:       297.33    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air sensitive, moisture sensitive solid.    
   Hazardous Polymerization:       no hazardous polymerization    
   Prolonged contact with air or moisture. Keep away from heat and ignition sources including open flame and
   Conditions to Avoid:
   electrostatic discharge.
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, and manganese oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in RTECS.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       Possible mutagen (as Mn)    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Flammable solids, Organic, N.O.S.    
   Hazard Class (CFR):       4.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1325    
   Shipping Name (IATA):       Flammable solid, Organic, N.O.S.    
   Hazard Class (IATA):       4.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1325    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: see category code N450 for reporting    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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