Cobalt sulfate
CAS No.: 10124-43-3
Synonyms:
Formula: CoSO4
Exact Mass: 154.88500
Molecular Weight: 154.99600
PSA: 88.64000
LogP: -0.25720
Cobalt sulfate 10124-43-3 MSDS

SECTION 1: Identification of the substance/mixture and of the company/undertaking
  Product identifiers
    Product name        : Cobalt atomic spectroscopy standard concentrate    
    1.00 g Co
    REACH No.        : A registration number is not available for this substance as the substance    
    or its uses are exempted from registration, the annual tonnage does not
    require a registration or the registration is envisaged for a later
    registration deadline.
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances    
  
  

SECTION 2: Hazards identification
  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008
    Corrosive to metals (Category 1), H290
    Respiratory sensitisation (Category 1), H334
    Skin sensitisation (Category 1), H317
    Germ cell mutagenicity (Category 2), H341
    Carcinogenicity, Inhalation (Category 1B), H350i
    Reproductive toxicity (Category 1B), H360F
    Acute aquatic toxicity (Category 1), H400
    Chronic aquatic toxicity (Category 1), H410
    For the full text of the H-Statements mentioned in this Section, see Section 16.
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    T Toxic        R49    
    T Toxic        R60    
    Xn Harmful        R68    
    Xn Harmful        R42/43    
    N Dangerous for the        R50/53    
    environment
    For the full text of the R-phrases mentioned in this Section, see Section 16.
  Label elements
  Labelling according Regulation (EC) No 1272/2008
    Pictogram
    Signal word        Danger    
    Hazard statement(s)
    H290        May be corrosive to metals.    
    H317        May cause an allergic skin reaction.    
    H334        May cause allergy or asthma symptoms or breathing difficulties if inhaled.    
    H341        Suspected of causing genetic defects.    
    H350i        May cause cancer by inhalation.    
    H360F        May damage fertility.    
    H410        Very toxic to aquatic life with long lasting effects.    
    Precautionary statement(s)
    P201        Obtain special instructions before use.    
    P261        Avoid breathing vapours.    
    P273        Avoid release to the environment.    
    P280        Wear protective gloves.    
    P308 + P313        IF exposed or concerned: Get medical advice/ attention.    
    P501        Dispose of contents/ container to an approved waste disposal plant.    
    Supplemental Hazard        none    
    Statements
    Restricted to professional users.
  According to European Directive 67/548/EEC as amended.
    Hazard symbol(s)        T Toxic    
    N Dangerous for the environment
    R-phrase(s)
    R49        May cause cancer by inhalation.    
    R60        May impair fertility.    
    R68        Possible risk of irreversible effects.    
    R42/43        May cause sensitisation by inhalation and skin contact.    
    R50/53        Very toxic to aquatic organisms, may cause long-term adverse effects in    
    the aquatic environment.
    S-phrase(s)
    S53        Avoid exposure - obtain special instructions before use.    
    S23        Do not breathe vapour.    
    S36/37        Wear suitable protective clothing and gloves.    
    S45        In case of accident or if you feel unwell, seek medical advice immediately    
    (show the label where possible).
    S61        Avoid release to the environment. Refer to special instructions/ Safety    
    data sheets.
    Restricted to professional users.
  Other hazards
    This substance/mixture contains no components considered to be either persistent, bioaccumulative and
    toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients
  Mixtures
    Synonyms        : Cobalt(II) sulfate    
  Hazardous ingredients according to Regulation (EC) No 1272/2008
    Component        Classification        Concentration    
  Cobalt sulphate hydrate Included in the Candidate List of Substances of Very High Concern (SVHC)
    according to Regulation (EC) No. 1907/2006 (REACH)
    CAS-No.        60459-08-7        Acute Tox. 4; Resp. Sens. 1; >= 10 - < 20 %    
    EC-No.        233-334-2        Skin Sens. 1; Muta. 2; Carc.    
    Index-No.        027-005-00-0        1B; Repr. 1B; Aquatic Acute 1;    
    Aquatic Chronic 1; H302,
    H317, H334, H341, H350i,
    H360F, H410
  Hazardous ingredients according to Directive 1999/45/EC
    Component        Classification        Concentration    
  Cobalt sulphate hydrate Included in the Candidate List of Substances of Very High Concern (SVHC)
    according to Regulation (EC) No. 1907/2006 (REACH)
    CAS-No.        60459-08-7        T, N, Carc.Cat.2, Repr.Cat.2, >= 10 - < 20 %    
    EC-No.        233-334-2        Mut.Cat.3, R49 - R60 - R22 -    
    Index-No.        027-005-00-0        R42/43 - R68 - R50/53    
    For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16

SECTION 4: First aid measures
  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
  In case of eye contact
    Flush eyes with water as a precaution.
  If swallowed
    Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
    The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
    section 11
  Indication of any immediate medical attention and special treatment needed
    No data available

SECTION 5: Firefighting measures
  Extinguishing media
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special hazards arising from the substance or mixture
    Sulphur oxides, Cobalt/cobalt oxides
  Advice for firefighters
    Wear self-contained breathing apparatus for firefighting if necessary.
  Further information
    No data available

SECTION 6: Accidental release measures
  Personal precautions, protective equipment and emergency procedures
    Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
    Evacuate personnel to safe areas.
    For personal protection see section 8.
  Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
    environment must be avoided.
  Methods and materials for containment and cleaning up
    Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
    containers for disposal.
  Reference to other sections
    For disposal see section 13.

SECTION 7: Handling and storage
  Precautions for safe handling
    Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation
    of vapour or mist.
    For precautions see section 2.2.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
    opened must be carefully resealed and kept upright to prevent leakage.
    Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous
    materials causing chronic effects
  Specific end use(s)
    Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection
  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
    at the end of workday.
  Personal protective equipment
  Eye/face protection
    Face shield and safety glasses Use equipment for eye protection tested and approved under
    appropriate government standards such as NIOSH (US) or EN 166(EU).
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
  Body Protection
    Complete suit protecting against chemicals, The type of protective equipment must be selected
    according to the concentration and amount of the dangerous substance at the specific workplace.
  Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
    with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
    to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
    respirator. Use respirators and components tested and approved under appropriate government
    standards such as NIOSH (US) or CEN (EU).
  Control of environmental exposure
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
    the environment must be avoided.

SECTION 9: Physical and chemical properties
  Information on basic physical and chemical properties
    a) Appearance        Form: liquid    
    Colour: light red
    b) Odour        No data available    
    c) Odour Threshold        No data available    
    d) pH        No data available    
    e) Melting point/freezing        No data available    
    point
    f) Initial boiling point and No data available
    boiling range
    g) Flash point        Not applicable    
    h) Evaporation rate        No data available    
    i) Flammability (solid, gas) No data available
    j) Upper/lower        No data available    
    flammability or
    explosive limits
    k) Vapour pressure        No data available    
    l) Vapour density        No data available    
    m) Relative density        1,000 g/cm3 at 20 °C    
    n) Water solubility        No data available    
    o) Partition coefficient: n- No data available
    octanol/water
    p) Auto-ignition        No data available    
    temperature
    q) Decomposition        No data available    
    temperature
    r) Viscosity        No data available    
    s) Explosive properties        No data available    
    t) Oxidizing properties        No data available    
  Other safety information
    No data available

SECTION 10: Stability and reactivity
  Reactivity
    No data available
  Chemical stability
    Stable under recommended storage conditions.
  Possibility of hazardous reactions
    No data available
  Conditions to avoid
    No data available
  Incompatible materials
    No data available
  Hazardous decomposition products
    Other decomposition products - No data available
    In the event of fire: see section 5

SECTION 11: Toxicological information
  Information on toxicological effects
  Acute toxicity
  Skin corrosion/irritation
    No data available
  Serious eye damage/eye irritation
    No data available
  Respiratory or skin sensitisation
    No data available
  Germ cell mutagenicity
    No data available
  Carcinogenicity
    IARC:        2B - Group 2B: Possibly carcinogenic to humans (Cobalt sulphate hydrate)    
    2B - Group 2B: Possibly carcinogenic to humans (Cobalt sulphate hydrate)
  Reproductive toxicity
    No data available
  Specific target organ toxicity - single exposure
    No data available
  Specific target organ toxicity - repeated exposure
    No data available
  Aspiration hazard
    No data available
  Additional Information
    RTECS: Not available
    May cause irritation of the:, nose, Throat., sensation of heat, Exposure can cause damage to the:, Kidney,
    Lungs, Thyroid

SECTION 12: Ecological information
  Toxicity
    No data available
  Persistence and degradability
    No data available
  Bioaccumulative potential
    No data available
  Mobility in soil
    No data available
  Results of PBT and vPvB assessment
    This substance/mixture contains no components considered to be either persistent, bioaccumulative and
    toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
  Other adverse effects
    Very toxic to aquatic life.

SECTION 13: Disposal considerations
  Waste treatment methods
  Product
    Offer surplus and non-recyclable solutions to a licensed disposal company.
  Contaminated packaging
    Dispose of as unused product.

SECTION 14: Transport information
  UN number
    ADR/RID: 3082        IMDG: 3082        IATA: 3082    
  UN proper shipping name
    ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cobalt sulphate
    hydrate)
    IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cobalt sulphate
    hydrate)
    IATA:        Environmentally hazardous substance, liquid, n.o.s. (Cobalt sulphate hydrate)    
  Transport hazard class(es)
    ADR/RID: 9        IMDG: 9        IATA: 9    
  Packaging group
    ADR/RID: III        IMDG: III        IATA: III    
  Environmental hazards
    ADR/RID: yes        IMDG Marine pollutant: yes        IATA: yes    
  Special precautions for user
  Further information
    EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
    packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

SECTION 15: Regulatory information
    This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
  Safety, health and environmental regulations/legislation specific for the substance or mixture
  Authorisations and/or restrictions on use
    Cobalt sulphate hydrate        CAS-No.: 60459-08-7    
    Candidate List of Substances of Very High Concern for Authorisation
    Carcinogenic (article 57a)
    ED/95/2010
    Cobalt sulphate hydrate        CAS-No.: 60459-08-7    
    REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).
    Carcinogenic (article 57a)
    ED/95/2010
  Chemical Safety Assessment
    For this product a chemical safety assessment was not carried out

SECTION 16: Other information
  Full text of H-Statements referred to under sections 2 and 3.
    Acute Tox.        Acute toxicity    
    Aquatic Acute        Acute aquatic toxicity    
    Aquatic Chronic        Chronic aquatic toxicity    
    Carc.        Carcinogenicity    
    H290        May be corrosive to metals.    
    H302        Harmful if swallowed.    
    H317        May cause an allergic skin reaction.    
    H334        May cause allergy or asthma symptoms or breathing difficulties if inhaled.    
    H341        Suspected of causing genetic defects.    
    H350i        May cause cancer by inhalation.    
    H360F        May damage fertility.    
    H400        Very toxic to aquatic life.    
    H410        Very toxic to aquatic life with long lasting effects.    
    Muta.        Germ cell mutagenicity    
    Repr.        Reproductive toxicity    
    Resp. Sens.        Respiratory sensitisation    
    Skin Sens.        Skin sensitisation    
  Full text of R-phrases referred to under sections 2 and 3
    N        Dangerous for the environment    
    R22        Harmful if swallowed.    
    R42/43        May cause sensitisation by inhalation and skin contact.    
    R49        May cause cancer by inhalation.    
    T        Toxic    
    R50/53        Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic    
    environment.
    R60        May impair fertility.    
    R68        Possible risk of irreversible effects.    
    Repr.Cat.2        Toxic to Reproduction Category 2    
  Further information
    Copyright 2014 Co. LLC. License granted to make unlimited paper copies for internal use
    only.
    The above information is believed to be correct but does not purport to be all inclusive and shall be
    used only as a guide. The information in this document is based on the present state of our knowledge
    and is applicable to the product with regard to appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Corporation and its Affiliates shall not be held
    liable for any damage resulting from handling or from contact with the above product. See
     and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

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