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Thallium(I) Nitrate
CAS No.: 10102-45-1
Synonyms:
Formula: NO3Tl
Exact Mass: 266.96200
Molecular Weight: 266.38800
PSA: 68.88000
LogP: 0.28410
Reference Price: $850/kg Inquiry Now
Thallium(I) Nitrate 10102-45-1 MSDS
Name: Thallium (I) Nitrate 99.5% Material Safety Data Sheet
Synonym: Thallous Nitrat
CAS: 10102-45-1
Section 1 - Chemical Product   MSDS Name:Thallium (I) Nitrate 99.5% Material Safety Data Sheet
Synonym:Thallous Nitrat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10102-45-1 Thallium (I) Nitrate 99.5 233-273-1
Hazard Symbols: T+ O
Risk Phrases: 26/28 33

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Very toxic by inhalation and if swallowed. Danger of cumulative effects.Oxidizer.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Excessive drying of the skin may result from repeated or prolonged contact. Absorbed through the skin.
Ingestion:
May be fatal if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage. Methemoglobinemia is characterized by dizziness, drowsiness, headache, shortness of breath, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), rapid heart rate and chocolate-brown colored blood. May cause alopecia (loss of hair).
Ingestion of nitrate containing compounds can lead to methemoglobinemia. Ingested thallium compounds are extremely toxic, causing convulsions, coma, conjunctivitis, runny nose, polyneuritis, motor and sensory peripheral neuropathy, encephalopathy, arterial hypertension, rapid heart rate, and skin eruptions Inhalation:
May cause liver and kidney damage. Causes upper respiratory tract irritation. Causes irritation of the mucous membrane.
Chronic:
May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. There is a danger of cumulative effects.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene Blue depending on the methemoglobin concentration in the blood.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Strong oxidizer. Contact with other material may cause fire. Use water with caution and in flooding amounts. May accelerate burning if involved in a fire. Containers may explode when heated.
Extinguishing Media:
Use water only! Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out. Do NOT use dry chemicals, CO2, Halon or foams.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. In case of spill, sweep up solid or absorb liquid with inert material, then place into a biohazard container.
Wear protective equipment.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Do not breathe dust, vapor, mist, or gas. Keep container tightly closed.
Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Use only in a chemical fume hood.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use only under a chemical fume hood.
Exposure Limits CAS# 10102-45-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 433 deg C @ 760.00mm Hg
Freezing/Melting Point: 206 deg C
Autoignition Temperature: Not available.
Flash Point: 450 deg C ( 842.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 450 deg C
Solubility in water: 95 G/L WATER (20C)
Specific Gravity/Density: 5.55 g/cm3
Molecular Formula: NO3Tl
Molecular Weight: 266.38

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, dust generation, combustible materials.
Incompatibilities with Other Materials:
Strong reducing agents, strong acids, cyanides (e.g. potassium cyanide, sodium cyanide), hypophosphites, thiocyanates, isothiocyanates.
Hazardous Decomposition Products:
Nitrogen oxides, irritating and toxic fumes and gases, thallium fumes.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 10102-45-1: XG5950000 LD50/LC50:
CAS# 10102-45-1: Oral, mouse: LD50 = 15 mg/kg.
Oral, man: TDLo = 73 mg/kg (Effects: hypermotility, diarrhea, nausea, vomiting and Carcinogenicity:
Thallium (I) Nitrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Bioconcentration factors for thallium: in freshwater plants, factor of 100,000; marine plants, factor of 100,000. Bioconcentration factors for thallium: in freshwater fish, factor of 100,000; in marine invertebrates, factor of 150,000; in marine fish, factor of 100,000;in clams (Mya arenia), factor of 17.6-18.6; in mussel (Mytilus edulis), factor of 10.9-12.4; and in Atlantic salmon, factor of 27-1430. No evidence was found for formation of volatile thallium compounds in the environment.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: THALLIUM NITRATE
Hazard Class: 6.1 (5.1)
UN Number: 2727
Packing Group: II
IMO
Shipping Name: THALLIUM NITRATE
Hazard Class: 6.1
UN Number: 2727
Packing Group: II
RID/ADR
Shipping Name: THALLIUM NITRATE
Hazard Class: 6.1
UN Number: 2727
Packing group: II
USA RQ: CAS# 10102-45-1: 100 lb final RQ; 45.4 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ O
Risk Phrases:
R 26/28 Very toxic by inhalation and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10102-45-1: 2
Canada
CAS# 10102-45-1 is listed on Canada's NDSL List.
CAS# 10102-45-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10102-45-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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