Recommended Suppliersmore
diphenyl ether 101-84-8 MSDS
Name: Phenyl ether 99% Material Safety Data Sheet
Synonym: Diphenyl ether, Diphenyl oxide; Biphenyloxide; Phenoxybenzene
CAS: 101-84-8
Section 1 - Chemical Product   MSDS Name:Phenyl ether 99% Material Safety Data Sheet
Synonym:Diphenyl ether, Diphenyl oxide; Biphenyloxide; Phenoxybenzene

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
101-84-8 Phenyl ether 99.0 202-981-2
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage.
Inhalation:
Causes respiratory tract irritation.
Chronic:
May cause liver and kidney damage. Prolonged or repeated exposure may cause thyroid damage. Repeated exposure may cause damage to the spleen.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing.
Avoid ingestion and inhalation.
Storage:
Keep away from heat and flame. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 101-84-8: United Kingdom, WEL - TWA: 1 ppm TWA (vapor); 7.1 mg/m3 TWA (vapo United Kingdom, WEL - STEL: 3 ppm STEL (vapor); 21.3 mg/m3 STEL (vapor) United States OSHA: 1 ppm TWA (vapor); 7 mg/m3 TWA (vapor) Belgium - TWA: 1 ppm VLE (vapor); 7 mg/m3 VLE (vapor) Belgium - STEL: 2 ppm VLE (vapor); 14 mg/m3 VLE (vapor) France - VME: 1 ppm VME; 7 mg/m3 VME Germany: 1 ppm TWA (steam); 7.1 mg/m3 TWA (steam) Russia: 5 mg/m3 TWA (vapour) Spain: 1 ppm VLA-ED (vapor); 7.1 mg/m3 VLA-ED (vapor) Spain: 2 ppm VLA-EC (vapor); 14.2 mg/m3 VLA-EC (vapor) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: Geranium odor.
pH: Not available.
Vapor Pressure: < 1 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 257 deg C
Freezing/Melting Point: 28 deg C
Autoignition Temperature: 1148 deg F ( 620.00 deg C)
Flash Point: 239 deg F ( 115.00 deg C)
Explosion Limits, lower: 1.5%
Explosion Limits, upper: 0.8%
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 1.073
Molecular Formula: C12H10O
Molecular Weight: 170.0694

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 101-84-8: KN8970000 LD50/LC50:
CAS# 101-84-8: Draize test, rabbit, eye: 10 ppm/140H; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, rat: LD50 = 2450 mg/kg; Oral, rat: LD50 = 4000 mg/kg; Skin, rabbit: LD50 = >7940 mg/kg.
Carcinogenicity:
Phenyl ether - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Fathead Minnow: LC50 = 4.0 mg/L; 96 hr.; flow-through bioassay

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 101-84-8: 2
Canada
CAS# 101-84-8 is listed on Canada's DSL List.
CAS# 101-84-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 101-84-8 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

Home   |   Announcement   |   Partners   |   Business Cooperation   |   Suppliers   |   Products    |   About Us   |   Contact Us   |   Privacy Policy   |   Terms & Conditions   |   Legal Statement

Copyright © 2013-2016 MOLBASE All Rights Reserved ICP Shanghai 14014220