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Manganese(II) sulfate monohydrate 10034-96-5 MSDS
Name: Manganese (II) Sulfate Monohydrate Reagent ACS Material Safety Data Sheet
Synonym: Manganese (II) Sulfate, Monohydrate, Manganous Sulfate Monohydrat
CAS: 10034-96-5
Section 1 - Chemical Product   MSDS Name:Manganese (II) Sulfate Monohydrate Reagent ACS Material Safety Data Sheet
Synonym:Manganese (II) Sulfate, Monohydrate, Manganous Sulfate Monohydrat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10034-96-5 Manganese Sulfate, Monohydrate >98 unlisted
Hazard Symbols: XN
Risk Phrases: 48/20/22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.Hygroscopic.
Potential Health Effects
Eye:
May cause mild eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic inhalation or ingestion may cause argyria characterized by blue-gray discoloration of the eyes, skin and mucous membrances.
Chronic skin contact may cause permanent discoloration of the skin.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Antidote: The use of Calcium disodium EDTA as a chelating agent should be determined by qualified medical personnel.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Material will not burn. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Appearance: pink
Odor: Odorless.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 850 deg C @ 760.00mm Hg
Freezing/Melting Point: 700 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 3.25@25C
Molecular Formula: MnSO4.H2O
Molecular Weight: 169.02

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Can react with strong acid, strong oxidizing agents, powdered metals; may react violently with hydrogen peroxide.
Hazardous Decomposition Products:
Carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide, oxides of manganese.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 10034-96-5: OP0893500 LD50/LC50:
Not available.
Carcinogenicity:
Manganese Sulfate, Monohydrate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Shipping Name: Not regulated.
Dangerous Goods Code:
UN Number:

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 48/20/22 Harmful : danger of serious damage to
health by prolonged exposure through inhalation and if
swallowed.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 10034-96-5: 1
United Kingdom Occupational Exposure Limits
CAS# 10034-96-5: OES-United Kingdom, TWA (listed as ** undefined
**): as Mn: 5 mg/m3 TWA
CAS# 10034-96-5: OES-United Kingdom, STEL (listed as ** undefined
**): fume, as Mn: 3 mg/m3 STEL
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10034-96-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 10034-96-5: OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL-BELGIUM:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL-CZECHOSLOVAKIA:TWA 2 mg(Mn)/m3;STEL 6 mg(Mn)/m3 JANUARY 1993
OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JANUARY 1993
OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JANUARY 1993
OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JANUARY 1993
OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JANUARY 1993
OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JANUARY 1993
OEL-POLAND:TWA 0.3 mg(Mn)/m3 JANUARY 1993
OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust)
OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust)
OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 10034-96-5 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).


SECTION 16 - ADDITIONAL INFORMATION
N/A

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