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antimony trichloride
CAS No.: 10025-91-9
Synonyms:
Formula: Cl3Sb
Exact Mass: 225.81000
Molecular Weight: 228.11900
PSA: 0.00000
LogP: 2.06850
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antimony trichloride 10025-91-9 MSDS
Name: Antimony Trichloride Material Safety Data Sheet
Synonym: Trichlorostibine; Antimonous chloride; Antimony(III) chloride; Antimony trichloride.
CAS: 10025-91-9
Section 1 - Chemical Product MSDS Name: Antimony Trichloride Material Safety Data Sheet
Synonym: Trichlorostibine; Antimonous chloride; Antimony(III) chloride; Antimony trichloride.
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10025-91-9 Antimony trichloride >99 233-047-2
Hazard Symbols: C N
Risk Phrases: 34 51/53
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes burns. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Corrosive.Moisture sensitive.Hygroscopic (absorbs moisture from the air). Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May be harmful if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract. May cause lung damage. May produce cardiovascular effects.
Chronic:
Chronic exposure may cause liver damage.
SECTION 4 - FIRST AID MEASURES
Eyes:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:


SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. May react with metals and lead to the formation of flammable hydrogen gas. Substance may react with water, and may release corrosive and/or toxic gases.
Extinguishing Media:
Do NOT get water inside containers. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. For small fires, use carbon dioxide, dry chemical, dry sand, or alcohol-resistant foam. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Keep away from metals. Corrosives area. Keep containers tightly closed.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits CAS# 10025-91-9: United Kingdom, WEL - TWA: (listed as antimony compounds): 0.5 mg TWA (except stibine, as Sb) United Kingdom, WEL - STEL: (listed as antimony compounds): 1.5 m STEL (except stibine, as Sb)
United States OSHA: 0.5 mg/m3 TWA (listed under Antimony).0.5 mg TWA (as Sb) (listed under Antimony compounds). Belgium - TWA: (listed as antimony compounds): 0.5 mg/m3 VLE (as France - VME: (listed as antimony compounds): 0.5 mg/m3 VME (as S
Germany: (listed as antimony compounds): 0.5 mg/m3 VME (as Sb)
Japan: (listed as antimony compounds): 0.1 mg/m3 OEL (except stib as Sb)
Malaysia: (listed as antimony compounds): 0.5 mg/m3 TWA (as Sb)
Netherlands: (listed as antimony compounds): 0.5 mg/m3 MAC (as Sb
Russia: 0.3 mg/m3 TWA
Russia: (listed as antimony): 0.2 mg/m3 STEL
Spain: (listed as antimony compounds): 0.5 mg/m3 VLA-ED (except antimony hydride, as Sb) Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white
Odor: pungent odor
pH: Not available.
Vapor Pressure: 1 mm Hg @ 49.2C
Viscosity: Not available.
Boiling Point: 223 deg C
Freezing/Melting Point: 73 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: soluble (but hydrolysis to SbOCl)
Specific Gravity/Density: 3.14
Molecular Formula: SbCl3
Molecular Weight: 228.11
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Imcompatible with aluminum, potassium and sodium, perchloric acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, irritating and toxic fumes and gases, antimony/antimony oxides.
Hazardous Polymerization: Has not been reported.
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 10025-91-9: CC4900000
LD50/LC50:
CAS# 10025-91-9: Oral, rat: LD50 = 525 mg/kg. Inhalation TCLo (human): 73 mg/m3.
Carcinogenicity:
Antimony trichloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
SECTION 14 - TRANSPORT INFORMATION IATA
Shipping Name: ANTIMONY TRICHLORIDE
Hazard Class: 8
UN Number: 1733
Packing Group: II IMO
Shipping Name: ANTIMONY TRICHLORIDE
Hazard Class: 8
UN Number: 1733
Packing Group: II RID/ADR
Shipping Name: ANTIMONY TRICHLORIDE
Hazard Class: 8
UN Number: 1733
Packing group: II
USA RQ: CAS# 10025-91-9: 1000 lb final RQ; 454 kg final RQ
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: C N
Risk Phrases:
R 34 Causes burns. R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# 10025-91-9: 2 Canada CAS# 10025-91-9 is listed on Canada's DSL List. CAS# 10025-91-9 is listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 10025-91-9 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 3/11/1999 Revision #5 Date: 6/01/2005 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A

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