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|Name:||Indium trichloride Material Safety Data Sheet|
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
Potential Health Effects
Soluble indium salts are very irritating to the eyes.
Causes skin irritation.
May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
Causes respiratory tract irritation. May cause pulmonary edema and severe respiratory disturbances.
The lungs of rats exposed daily to In2O3 at concentrations from 24-97 mg/m3 for a total of 224 hrs showed evidence of widespread alveolar edema, which differs from the usual toxic edema fluid by being granular and containing a few alveolar phagocytes, polymorphonuclear cells, & nuclear debris. The injury was further characterized by alteration of the alveolar walls by spindle-shaped & other type cells. The lesion showed little change either during exposure or after a 12-week postexposure period, & no fibrosis resulted from the healing process. Thus, In2O3 dust uniquely produces a widespread alveolar stasis resembling alveolar proteinosis in which alveolar clearance is reduced. Associated chronic respiratory insufficiency, recurrent acute pneumonitis, or complicating infections may result in a fatal outcome.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products.
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.
Section 7 - HANDLING and STORAGE
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Store in a cool, dry place. Keep container closed when not in use.
Store protected from moisture.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 10025-82-8: United Kingdom, WEL - TWA: (listed as indium compounds, n.o.s.): mg/m3 TWA (as In) United Kingdom, WEL - STEL: (listed as indium compounds, n.o.s.): mg/m3 STEL (as In) Belgium - TWA: (listed as indium compounds, n.o.s.): 0.1 mg/m3 VL (as In) Malaysia: (listed as indium compounds, n.o.s.): 0.01 mg/m3 TWA (a In) Netherlands: (listed as indium compounds, n.o.s.): 0.1 mg/m3 MAC In) Spain: (listed as indium compounds, n.o.s.): 0.1 mg/m3 VLA-ED (as Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Powder
Color: white to pale yellow
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 800 deg C
Freezing/Melting Point: 500 deg C (sublimes)
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Freely Soluble.
Specific Gravity/Density: 4.0
Molecular Formula: Cl3In
Molecular Weight: 221.18
Section 10 - STABILITY AND REACTIVITY
Stable under normal temperatures and pressures. Deliquescent (tending to absorb atmospheric water vapor and become liquid).
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
No information found..
Hazardous Decomposition Products:
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
CAS# 10025-82-8: NL1400000 LD50/LC50:
Indium chloride - Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
Shipping Name: Not regulated.
Shipping Name: Not regulated.
Shipping Name: Not regulated.
Section 15 - REGULATORY INFORMATION
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
WGK (Water Danger/Protection)
CAS# 10025-82-8: No information available.
CAS# 10025-82-8 is listed on Canada's DSL List.
CAS# 10025-82-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 10025-82-8 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION