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cadmium nitrate tetrahydrate 10022-68-1 MSDS
Name: Cadmium Nitrate Tetrahydrate Material Safety Data Sheet
Synonym: Nitric acid, cadmium salt, tetrahydrate
CAS: 10022-68-1
Section 1 - Chemical Product   MSDS Name:Cadmium Nitrate Tetrahydrate Material Safety Data Sheet
Synonym:Nitric acid, cadmium salt, tetrahydrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10022-68-1 Cadmium nitrate tetrahydrate >98 unlisted
Hazard Symbols: XN O N
Risk Phrases: 20/21/22 40 8 50/53

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect. Contact with combustible material may cause fire. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes severe skin irritation.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause unconsciousness.
Inhalation:
Effects may be delayed. Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions, tachycardia, dyspnea (labored breathing), and death. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause dyspnea (difficult or labored breathing). May cause anemia. May cause cough, chest pain, fever, muscular cramps, and headache.
Chronic:
May cause respiratory tract cancer. Prolonged or repeated exposure may cause permanent bone structure abnormalities. May cause anemia and other blood cell abnormalities. Chronic inhalation may cause pulmonary emphysema. The primary target organ for chronic cadmium disease is clearly the kidney.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Antidote: The use of Calcium disodium EDTA as a chelating agent should be determined by qualified medical personnel.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation. Do not use combustible materials such as paper towels to clean up spill.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Use with adequate ventilation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. See 29CFR 1910.1027 for regulations applying to all occupational exposures to cadmium and cadmium compounds, in all forms.
Exposure Limits CAS# 10022-68-1: United Kingdom, WEL - TWA: (listed as cadmium compounds): 0.025 m TWA (except cadmium oxide fume, cadmium sulphide, cadmium sulphid United Kingdom, WEL - STEL: (listed as cadmium compounds): 0.075 mg/m3 STEL (except cadmium oxide fume, cadmium sulphide, cadmium sulphide United States OSHA: 2.5 g/m3 Action Level (as Cd); 5 g/m3 PEL ( Cd. Do not eat, drink or chew t obacco or gum or apply cosmetics regulated areas. Carcinogen: dust can cause lung and kidney disease. See 29 CFR 1910.1027) (listed under Cadmium compounds).
Belgium - TWA: (listed as cadmium compounds): 0.002 mg/m3 VLE (respirable particulates, as Cd); 0.01 mg/m3 VLE (inhalable part France - VME: (listed as cadmium compounds): 0.05 mg/m3 VME (as C Germany: (listed as cadmium compounds): 0.05 mg/m3 VME (as Cd) Japan: (listed as cadmium compounds): 0.05 mg/m3 OEL (as Cd) Malaysia: (listed as cadmium compounds): 0.01 mg/m3 TWA (as Cd); 0.002 mg/m3 TWA (respirable fraction, as Cd) Netherlands: (listed as cadmium inorganic compounds): 0.005 mg/m3 (as Cd) Russia: (listed as cadmium compounds): 0.05 mg/m3 TWA (as Cd) Russia: (listed as cadmium compounds): 0.01 mg/m3 STEL (as Cd) Spain: (listed as cadmium compounds): 0.01 mg/m3 VLA-ED (inhalabl fraction, except cadmium sulfoselenide and cadmium CAS# 10325-94-7: United Kingdom, WEL - TWA: (listed as cadmium compounds): 0.025 m TWA (except cadmium oxide fume, cadmium sulphide, cadmium sulphid United Kingdom, WEL - STEL: (listed as cadmium compounds): 0.075 mg/m3 STEL (except cadmium oxide fume, cadmium sulphide, cadmium sulphide United States OSHA: 2.5 g/m3 Action Level (as Cd); 5 g/m3 PEL ( Cd. Do not eat, drink or chew t obacco or gum or apply cosmetics regulated areas. Carcinogen: dust can cause lung and kidney disease. See 29 CFR 1910.1027) (listed under Cadmium compounds).
Belgium - TWA: (listed as cadmium compounds): 0.002 mg/m3 VLE (respirable particulates, as Cd); 0.01 mg/m3 VLE (inhalable part France - VME: (listed as cadmium compounds): 0.05 mg/m3 VME (as C Germany: (listed as cadmium compounds): 0.05 mg/m3 VME (as Cd) Japan: (listed as cadmium compounds): 0.05 mg/m3 OEL (as Cd) Malaysia: (listed as cadmium compounds): 0.01 mg/m3 TWA (as Cd); 0.002 mg/m3 TWA (respirable fraction, as Cd) Russia: (listed as cadmium compounds): 0.05 mg/m3 TWA (as Cd) Russia: (listed as cadmium compounds): 0.01 mg/m3 STEL (as Cd) Spain: (listed as cadmium compounds): 0.01 mg/m3 VLA-ED (inhalabl fraction, except cadmium sulfoselenide and cadmium Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 132 deg C
Freezing/Melting Point: 59 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 215% (20 C)
Specific Gravity/Density: 2.455 @ 17C
Molecular Formula: Cd(NO3)2.4H2O
Molecular Weight: 308.47

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable.
Conditions to Avoid:
Dust generation, confined spaces.
Incompatibilities with Other Materials:
Strong reducing agents, combustible materials.
Hazardous Decomposition Products:
Nitrogen oxides, toxic cadmium oxide fumes.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 10022-68-1: EV1850000 CAS# 10325-94-7: EV1750000 LD50/LC50:
CAS# 10022-68-1: Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Severe; Oral, rat: LD50 = 300 mg/kg.
CAS# 10325-94-7: Oral, mouse: LD50 = 47 mg/kg; Oral, rat: LD50 = 300 mg/kg.
Carcinogenicity:
Cadmium nitrate tetrahydrate - California: carcinogen, initial date 10/1/87 (listed as Cadmium compou NTP: Known carcinogen (listed as Cadmium compounds).
IARC: Group 1 carcinogen (listed as Cadmium compounds).
Cadmium nitrate anhydrous - California: carcinogen, initial date 10/1/87 (listed as Cadmium compou NTP: Known carcinogen (listed as Cadmium compounds).
IARC: Group 1 carcinogen (listed as Cadmium compounds).
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Fish: Rainbow trout: 55ug/L; 48HFish: Fathead Minnow: 820ug/L; 48H

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
IMO
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
RID/ADR
Shipping Name: NITRATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1477
Packing group: II

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 22 Do not breathe dust.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 10022-68-1: No information available.
CAS# 10325-94-7: 3
Canada
CAS# 10325-94-7 is listed on Canada's DSL List.
CAS# 10022-68-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 10325-94-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10022-68-1 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 10325-94-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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