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anisole
CAS No.: 100-66-3
Synonyms:
Formula: C7H8O
Exact Mass: 108.05800
Molecular Weight: 108.13800
PSA: 9.23000
LogP: 1.69520
Reference Price: $2,984/ton Inquiry Now
anisole 100-66-3 MSDS
Name: Anisole Material Safety Data Sheet
Synonym: Methoxybenzene; Benzene, methoxy; Ethyl, methyl phenyl; Methyl phenyl ether; Phenyl methyl ethe
CAS: 100-66-3
Section 1 - Chemical Product   MSDS Name:Anisole Material Safety Data Sheet
Synonym:Methoxybenzene; Benzene, methoxy; Ethyl, methyl phenyl; Methyl phenyl ether; Phenyl methyl ethe

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
100-66-3 Anisole 100.0 202-876-1
Hazard Symbols: XN XI F
Risk Phrases: 10 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.Flammable liquid.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation. Causes eye irritation.
Skin:
May cause skin irritation. Causes moderate skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause respiratory tract irritation. Vapors may cause dizziness or suffocation.
Chronic:
May cause kidney injury. Chronic exposure may lead to liver and lung damage. Laboratory experiments have resulted in mutagenic effects.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water.
Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained. Use water spray, dry chemical, carbon dioxide, or chemical foam. Do NOT use straight streams of water.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Use a spark-proof tool. A vapor suppressing foam may be used to reduce vapors.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not allow contact with water. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 100-66-3: Russia: 10 mg/m3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless - clear straw colored
Odor: Agreeable, aromatic odor.
pH: Not available.
Vapor Pressure: 10 mm Hg @ 42.2 C
Viscosity: 1.52 cps @ 15 C
Boiling Point: 154 deg C @ 760.00mm Hg
Freezing/Melting Point: -37 deg C
Autoignition Temperature: 475 deg C ( 887.00 deg F)
Flash Point: 41 deg C ( 105.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .9950g/cm3
Molecular Formula: C7H8O
Molecular Weight: 108.14

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Mechanical shock, incompatible materials, ignition sources, temperatures above 50C (122F), exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 100-66-3: BZ8050000 LD50/LC50:
CAS# 100-66-3: Draize test, rabbit, skin: 500 mg/24H Moderate; Inhalation, mouse: LC50 = 3021 mg/m3/2H; Inhalation, mouse: LC50 = 3020 mg/m3/2H; Inhalation, rat: LC50 = >5000 mg/m3; Inhalation, rat: LC50 = 8949 mg/m3/2H; Oral, mouse: LD50 = 2800 mg/kg; Oral, mouse: LD50 = 2900 mg/kg; Oral, rat: LD50 = 3700 mg/kg; Oral, rat: LD50 = 5290 mg/kg.
Carcinogenicity:
Anisole - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 18.8 mg/L; 30 Minutes; Microtox testEstimate BCF value = 24. This value along with its metabolism in aquatic organisms would indicate that Anisole has a low potential for bioconcentration in fish and aquatic organisms.
Estimate Koc value = 35. This value suggests that Anisole is highly mobile in soil and may readily leach. It was biodegradable in a screening test and therefore may readily biodegrade in soil.

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: ANISOLE
Hazard Class: 3
UN Number: 2222
Packing Group: III
IMO
Shipping Name: ANISOLE
Hazard Class: 3
UN Number: 2222
Packing Group: III
RID/ADR
Shipping Name: ANISOLE
Hazard Class: 3
UN Number: 2222
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN XI F
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 100-66-3: 2
Canada
CAS# 100-66-3 is listed on Canada's DSL List.
CAS# 100-66-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-66-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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