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4-nitroanisole
CAS No.: 100-17-4
Synonyms:
Formula: C7H7NO3
Exact Mass: 153.04300
Molecular Weight: 153.13500
PSA: 55.05000
LogP: 2.12660
Reference Price: $49/kg Inquiry Now
4-nitroanisole 100-17-4 MSDS
Name: 4-Nitroanisole 99+% Material Safety Data Sheet
Synonym: 1-Methoxy-4-nitrobenzene
CAS: 100-17-4
Section 1 - Chemical Product   MSDS Name:4-Nitroanisole 99+% Material Safety Data Sheet
Synonym:1-Methoxy-4-nitrobenzene

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
100-17-4 4-Nitroanisole >99 202-825-3
Hazard Symbols: XN
Risk Phrases: 40

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
May cause eye irritation. May cause eye burns.
Skin:
May cause skin irritation. If absorbed, causes symptoms similar to those of ingestion. May cause skin burns. Effects may be delayed.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Effects may be delayed. May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
For large fires, use water spray, fog, or alcohol-resistant foam.
For small fires, use dry chemical, carbon dioxide, halon, or water spray.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 100-17-4: Russia: 3 mg/m3 TWA Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 260 deg C
Freezing/Melting Point: 54 deg C
Autoignition Temperature: 458 deg C ( 856.40 deg F)
Flash Point: 130 deg C ( 266.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.2330
Molecular Formula: C7H7NO3
Molecular Weight: 153.14

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 100-17-4: BZ8800000 LD50/LC50:
CAS# 100-17-4: Oral, rat: LD50 = 2300 mg/kg; Skin, rat: LD50 = >16 gm/kg.
Carcinogenicity:
4-Nitroanisole - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Ecotoxicity:
Water danger/protection: WGK2 Invertebrate toxicity: EC50 (24 hr) Daphnia magna 13 mg/l (nominal value) [Kuehn, R. et al Water Res.
1989, 23(4), 501-510]

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: NITROANISOLE, SOLID
Hazard Class: 6.1
UN Number: 2730
Packing Group: III
IMO
Shipping Name: NITROANISOLE, SOLID
Hazard Class: 6.1
UN Number: 2730
Packing Group: III
RID/ADR
Shipping Name: NITROANISOLE
Hazard Class: 6.1
UN Number: 2730
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 100-17-4: 1
Canada
CAS# 100-17-4 is listed on Canada's NDSL List.
CAS# 100-17-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-17-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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